Manipulating Molecular Structure to Trigger Ultrafast and Long-Life Potassium Storage of Fe0.4 Ni0.6 S Solid Solution.

Currently, the main obstacle to the widespread utilization of metal chalcogenides (MSx ) as anode for potassium-ion batteries (PIBs) is their poor rate capability and inferior cycling stability as a result of the undesirable electrical conductivity and severe pulverization of the nanostructure during large K-ions intercalation-extraction processes. Herein, an ultrafast and long-life potassium storage of metal chalcogenide is rationally demonstrated by employing Fe0.4 Ni0.6 S solid-solution (FNS/C) through molecular structure engineering. Benefiting from improved electroactivity and intense interactions within the unique solid solution phase, the electrical conductivity and structure durability of Fe0.4 Ni0.6 S are vastly improved. As anticipated, the FNS/C electrode delivers superior rate properties (538.7 and 210.5 mAh g-1 at 0.1 and 10 A g-1 , respectively) and long-term cycle stability (180.8 mAh g-1 at 5 A g-1 after 2000 cycles with a capacity decay of 0.011% per cycle). Moreover, the potassium storage mechanisms of Fe0.4 Ni0.6 S solid solution are comprehensively revealed by several in situ characterizations and theoretical calculations. This innovative molecular structure engineering strategy opens avenues to achieve high-quality metal chalcogenides for future advanced PIBs.

Ultrahigh initial coulombic efficiency for deep sodium storage enabled by carbon-free vanadium-doping MoS2 hierarchical nanostructure.

Molybdenum disulfide (MoS2) has garnered attention as a promising anode material for sodium-ion batteries due to its high theoretical capacity and unique lamellar texture. Nevertheless, unmodified MoS2 suffers from inferior electrical conductivity, poor reaction reversibility, and suboptimal cycle life upon repeated sodiation/desodiation. In this study, a novel carbon-free V-heteroatom doping MoS2 composite (abbr. VMS) with hierarchical laurustinus-like structure was synthesized by a facile one-step hydrothermal process. Specifically, the rational doping of V-atoms can effectively modulate the intrinsic electronic structure of pure MoS2, resulting in enhanced Na-ion diffusion rate, improved reaction kinetics and reduced activation energy compared to bare MoS2. Additionally, the hierarchical structure of the VMS composite, with sufficient spacing, effectively mitigates mechanical stress and ensures the integrity of active materials. Consequently, the prepared VMS composite possesses exceptional reaction reversibility (average ICE value of 92 %) and remarkable capacity retention (92.1 % after 450 cycles at 10 A/g). These findings contribute valuable insights into the development of advanced MoS2-based anode for sodium ion batteries.