Intramolecularly O,N,O-Coordinated Tin(II) Salts: Syntheses, Structures, Cyclization, and Transition Metal Complexation.

We report the syntheses of tin(II) salts of the types [L1SnX]SnX3 [L1=2,6-{(i-PrO)2(O)P}2C5H3N: 1, X=Cl; 2, X=Br], [L2SnCl]SnCl3 [L2=2-{(i-PrO)Ph(O)P}-6-{(i-PrO)2(O)P}C5H3N: 3], [L3SnX]SnX3 [L3=2,6-{MeO(O)C}2C5H3N: 4, X=Cl; 5, X=Br], [L4SnX]SnX3 [L4=2,6-{Et2N(O)C}2C5H3N: 6, X=Cl; 7, X=Br]. These compounds were obtained by addition of SnX2 to the corresponding ligand inducing autoionization of the respective tin(II) halide. The thermal stability of 1, 3, and 4 was elucidated, giving, under ester cleavage and cyclisation, the tin(II) derivatives 8-12. The reaction of [L1SnCl]SnCl3 (1) with W(CO)4(thf)2 afforded the tungsten tetracarbonyl complex [{L1SnCl}{SnCl3}W(CO)4] (13), representing the first example in which a tin(II) stannate anion and a tin(II) stannylium cation simultaneously coordinate to a transition metal centre. The compounds were characterized by single crystal X-ray diffraction analyses and in part by elemental analyses, IR and NMR spectroscopy, electrospray ionization mass spectrometry. DFT calculations accompany the experimental work.

Identifying the ν=5/2 Topological Order through Charge Transport Measurements.

We propose an experiment to identify the topological order of the ν=5/2 state through a measurement of the electric conductance of a mesoscopic device. Our setup is based on interfacing ν=2,5/2, and 3 in the same device. Its conductance can unambiguously establish or rule out the particle-hole symmetric Pfaffian topological order, which is supported by recent thermal measurements. Additionally, it distinguishes between the Moore-Read and anti-Pfaffian topological orders, which are favored by numerical calculations.

Time-Crystalline Topological Superconductors.

Time crystals form when arbitrary physical states of a periodically driven system spontaneously break discrete time-translation symmetry. We introduce one-dimensional time-crystalline topological superconductors, for which time-translation symmetry breaking and topological physics intertwine-yielding anomalous Floquet Majorana modes that are not possible in free-fermion systems. Such a phase exhibits a bulk magnetization that returns to its original form after two drive periods, together with Majorana end modes that recover their initial form only after four drive periods. We propose experimental implementations and detection schemes for this new state.

Temperature Enhancement of Thermal Hall Conductance Quantization.

The quest for non-Abelian quasiparticles has inspired decades of experimental and theoretical efforts, where the scarcity of direct probes poses a key challenge. Among their clearest signatures is a thermal Hall conductance with quantized half-integer value in units of κ_{0}=π^{2}k_{B}^{2}T/3h (T is temperature, h the Planck constant, k_{B} the Boltzmann constant). Such values were recently observed in a quantum-Hall system and a magnetic insulator. We show that nontopological "thermal metal" phases that form due to quenched disorder may disguise as non-Abelian phases by well approximating the trademark quantized thermal Hall response. Remarkably, the quantization here improves with temperature, in contrast to fully gapped systems. We provide numerical evidence for this effect and discuss its possible implications for the aforementioned experiments.

Theory of Disorder-Induced Half-Integer Thermal Hall Conductance.

The thermal Hall conductance in the half-filled first Landau level was recently measured to take the quantized noninteger value κ_{xy}=5/2 (in units of temperature times π^{2}k_{B}^{2}/3h), which indicates a non-Abelian phase of matter. Such exotic states have long been predicted to arise at this filling factor, but the measured value disagrees with numerical studies, which predict κ_{xy}=3/2 or 7/2. We resolve this contradiction by invoking the disorder-induced formation of mesoscopic puddles with locally κ_{xy}=3/2 or 7/2. Interactions between these puddles generate a coherent macroscopic state that exhibits a plateau with quantized κ_{xy}=5/2. The non-Abelian quasiparticles characterizing this phase are distinct from those of the microscopic puddles and, by the same mechanism, could even emerge from a system comprised of microscopic Abelian puddles.

Anomalous Quasiparticle Symmetries and Non-Abelian Defects on Symmetrically Gapped Surfaces of Weak Topological Insulators.

We show that boundaries of 3D weak topological insulators can become gapped by strong interactions while preserving all symmetries, leading to Abelian surface topological order. The anomalous nature of weak topological insulator surfaces manifests itself in a nontrivial action of symmetries on the quasiparticles; most strikingly, translations change the anyon types in a manner impossible in strictly 2D systems with the same symmetry. As a further consequence, screw dislocations form non-Abelian defects that trap Z_{4} parafermion zero modes.

Explicit Derivation of Duality between a Free Dirac Cone and Quantum Electrodynamics in (2+1) Dimensions.

We explicitly derive the duality between a free electronic Dirac cone and quantum electrodynamics in (2+1) dimensions (QED_{3}) with N=1 fermion flavors. The duality proceeds via an exact, nonlocal mapping from electrons to dual fermions with long-range interactions encoded by an emergent gauge field. This mapping allows us to construct parent Hamiltonians for exotic topological-insulator surface phases, derive the particle-hole-symmetric field theory of a half-filled Landau level, and nontrivially constrain QED_{3} scaling dimensions. We similarly establish duality between bosonic topological insulator surfaces and N=2 QED_{3}.

Bosonic Analogue of Dirac Composite Fermi Liquid.

We introduce a particle-hole-symmetric metallic state of bosons in a magnetic field at odd-integer filling. This state hosts composite fermions whose energy dispersion features a quadratic band touching and corresponding 2π Berry flux protected by particle-hole and discrete rotation symmetries. We also construct an alternative particle-hole symmetric state-distinct in the presence of inversion symmetry-without Berry flux. As in the Dirac composite Fermi liquid introduced by Son [Phys. Rev. X 5, 031027 (2015)], breaking particle-hole symmetry recovers the familiar Chern-Simons theory. We discuss realizations of this phase both in 2D and on bosonic topological insulator surfaces, as well as signatures in experiments and simulations.

Facile one-pot synthesis and in silico study of new heterocyclic scaffolds with 4-pyridyl moiety: Mechanistic insights and X-ray crystallographic elucidation.

4-Acetylpyridine 1 and malononitrile 2 were allowed to react in a 3MCRs with dimedone 3a or cyclohexa-1,3-dione 3b under reflux to afford 4-methyl-4-(pyridin-4-yl)-5,6,7,8-tetrahydro-4H-chromene derivatives 4a,b respectively. The mechanism of the reaction has been studied and the structures elucidated by analytical, spectral as well as X-ray crystallographic data. Heterocyclic compounds find widespread application in pharmaceutical and agrochemical products. Docking analyses were performed on the synthesized compounds to assess their binding modes with various amino acids of the target protein tubulin (PDB Code - 1SA0). The results indicated promising binding scores for compounds 4a and 4b, suggesting a strong affinity for the tubulin binding site. Finally, ADMET for the synthesized compounds 4a, 4b, 5, 8a and 8b were carried out. The drug likeness and pharmacokinetic properties of the prepared compounds were also evaluated. Notably, all of the novel compounds adhered to Lipinski's rule (Ro5) without any violations.

Theory of a continuous stripe melting transition in a two-dimensional metal: a possible application to cuprate superconductors.

We construct a theory of continuous stripe melting quantum phase transitions in two-dimensional metals and the associated Fermi surface reconstruction. Such phase transitions are strongly coupled but yet theoretically tractable in situations where the stripe ordering is destroyed by proliferating doubled dislocations of the charge stripe order. The resulting non-Landau quantum critical point has strong stripe fluctuations which we show decouple dynamically from the Fermi surface even though static stripe ordering reconstructs the Fermi surface. We discuss connections to various stripe phenomena in the cuprates. We point out several puzzling aspects of old experimental results [G. Aeppli et al., Science 278, 1432 (1997)] on singular stripe fluctuations in the cuprates, and provide a possible explanation within our theory. These results may thus have been the first observation of non-Landau quantum criticality in an experiment.

Distinguishing between non-abelian topological orders in a quantum Hall system.

Quantum Hall states can harbor exotic quantum phases. The nature of these states is reflected in the gapless edge modes owing to "bulk-edge" correspondence. The most studied putative non-abelian state is the spin-polarized filling factor (ν) = 5/2, which permits different topological orders that can be abelian or non-abelian. We developed a method that interfaces the studied quantum state with another state and used it to identify the topological order of ν = 5/2 state. The interface between two half-planes, one hosting the ν = 5/2 state and the other an integer ν = 3 state, supports a fractional ν = 1/2 charge mode and a neutral Majorana mode. The counterpropagating chirality of the Majorana mode, probed by measuring partition noise, is consistent with the particle-hole Pfaffian (PH-Pf) topological order and rules out the anti-Pfaffian order.