Decolorization of water through removal of methylene blue and malachite green on biodegradable magnetic Bauhinia variagata fruits.

Batch sorption experiments were performed to investigate the potential of Bauhinia variagata fruit (BVf) and nano-magnetic Bauhinia variagata fruit (nM-BVf) to remove methylene blue (MB) and malachite green (MG). Equilibrium studies have been carried out using various experimental parameters such as the amount of biosorbent, initial solution concentration, contact time, pH, and temperature. The Langmuir, Freundlich, Scatchard, D-R and Temkin adsorption models were applied for the experimental information of MB and MG. The Freundlich model fits better than the Langmuir model. Freundlich model confirmed the magnificent dye sorption ability; 19.3 mg/g for BVf/MB, 21.2 mg/g for nM-BVf/MB, 19.7 mg/g for BVf/MG, and 30.1 mg/g for nM-BVf/MG. The pseudo-second-order kinetic model displayed a more suitable behavior to the experimental result for the removal of MG and MB. Thermodynamic parameters such as changes in Gibbs free energy (ΔGo), enthalpy (ΔHo), and entropy (ΔSo) were investigated and the fine details in the adsorption system were completed. The conclusion from this study is that the prepared nano biosorbent can be efficient for the removal of cationic dyes from wastewater.

Biosorption of methylene blue and malachite green on biodegradable magnetic Cortaderia selloana flower spikes: modeling and equilibrium study.

This study involves the production of a novel biosorbent obtained from Cortaderia selloana flower spikes (CSFs). Magnetic C. selloana flower spikes (nM∞CSFs) was applied as an ideal biosorbent for the elimination of dyes from water. They were utilized for the removal from aqueous solutions of malachite green (MG) and methylene blue (MB) dyes. The analyses of the equilibrium were done under certain experimental parameters such as contact time, initial dye concentration, pH, and quantity of biosorbent. The rapid intake of dyes to reach the equilibrium in a short period time showed the effectiveness of nM∞CSFs to adsorb MG and MB. The experimental information of MB and MG was obtained from the Langmuir model and it confirmed the magnificent dye biosorption ability; 72.99 mg/g for CSFs/MB, 119.05 mg/g for nM∞CSFs/MB, 31.06 mg/g for CSFs/MG, and 56.50 mg/g for nM∞CSFs/MG. Langmuir's model affirmed the excellent dye biosorption ability. The pseudo-second-order kinetic model displayed a great fit to the experimental result for the removal of MG and MB. The nM∞CSFs compared with raw biosorbent affirmed that the magnetic form of the biosorbent has a greater removal ability for MB and MG. nM∞CSFs is a noteworthy biosorbent for MB and MG removal from wastewater. [Figure: see text] HIGHLIGHTS Magnetic Cortaderia selloana flower spikes (nM∞CSFs) was synthesized for the biosorption of dyes FT-IR and SEM analysis were used for characterization. The Langmuir isotherm model fitted the data of the adsorption for nM∞CSFs nM∞CSFs is a noteworthy biosorbent for MB and MG removal from wastewater. A NOVELTY STATEMENT This novel biodegradable biosorbent (magnetic-C. selloana flower spikes-(nM∞CSFs)) has many different functional groups to bind MG and MB from aqueous medium. The method to bring the magnetic form was well described and gives an astronomically immense capacity for the abstraction of the dyes. It resists in acidic or basic medium and has a vigorous structure. It has an immense capacity for the dyes compared to other biosorbents. It can be cited by a sizably voluminous number of investigators or researchers when it is published because it is incipient biosorbent in the literature and can be utilized as a novel biosorbent for the removal of dyes.

Fast decolorization of cationic dyes by nano-scale zero valent iron immobilized in sycamore tree seed pod fibers: kinetics and modelling study.

In the present work, Sycamore (Platanus occidentalis) tree seed pod fibers (STSPF) and nano-scale zero valent iron particles (nZVI) immobilized in Sycamore tree seed pod fibers (nZVIʘSTSPF) were produced. This biosorbent has been utilized as a viable effective biosorbent in the removing of methylene blue hydrate (MB), malachite green oxalate(MG), methyl violet 2B(MV) dyes from synthetic wastewater. The biosorbents were characterized by scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. Various parameters such as contact time, solution concentration, pH and amount of biosorbent were investigated in order to evaluate the potential of the nanomaterials immobilized on natural wastes as sorbing biomaterials for the cationic dyes. Study on sorption kinetic and the sorption isotherm was carried out and best fitting models for the rate kinetics and isotherms were suggested. Langmuir isotherm was observed to be compatible with the isotherm models. The STSPF in the raw form showed the best dye sorption capacity of 43.67 mg/g for MG, 25.32 mg/g for MV, and 126.60 mg/g for MB. The magnetic nZVIʘSTSPF showed the best dye sorption capacity 92.59 mg/g for MG, 92.59 mg/g for MV, and 140.80 mg/g for MB. The iron nanoparticles immobilized biosorbent exhibited a higher removal capacity for all dyes compared to the raw biosorbent.

Chitosan-coated black sesame (Sesamum indicum L.) seed pulp as a novel candidate adsorbent for Cr(VI) elimination.

This study evaluates the application of Cr(VI) adsorption from the prepared synthetic solution by black sesame (Sesamum indicum L.) seed pulp (BSSP) and chitosan (Cts)-coated black sesame seed pulp beads (Cts-BSSP). BSSP and Cts-BSSP were used as an adsorbent without any chemical or physical treatment to remove Cr(VI) from an aqueous medium. The results indicated that the Cr(VI) removal was pH-dependent and reached an optimum at pH 2.0. It has been observed that the percentage of adsorption increased from 62% to 95% when the amount of Cts-BSSP increased from 0.0125 g to 0.0250 g. The required adsorbent amount for the maximum removal was 0.05 g and 0.1 g for Cst-BSSP and BSSP, respectively. The contact time for the adsorption was 120 min and 90 min for BSSP and Cst-BSSP, respectively. Scanning electron microscopy and Fourier transform infrared spectroscopy were used to explore the possible adsorption mechanism for Cr(VI). The equilibrium data for the BSSP and Cts-BSSP were used with the Langmuir and Freundlich adsorption isotherm models to assess the adsorption capacity and relevant mechanism. The adsorption capacity of the Cts-BSSP for Cr(VI) is relatively high compared to BSSP. The monolayer maximum adsorption capacities for Cr(VI) ions were 31.44 and 18.32 mg/g for Cts-BSSP and BSSP, respectively.

Synthesis of iron oxyhydroxide-coated rice straw (IOC-RS) and its application in arsenic(V) removal from water.

Because of the recognition that arsenic (As) at low concentrations in drinking water causes severe health effects, the technologies of As removal have become increasingly important. In this study, a simplified and effective method was used to immobilize iron oxyhydroxide onto a pretreated naturally occurring rice straw (RS). The modified RS adsorbent was characterized, using scanning electron microscope, Fourier transform infrared spectroscopy, thermogravimetric analyzer, and surface area analyzer. Experimental batch data of As(V) adsorption were modeled by the isotherms and kinetics models. Although all isotherms, the Langmuir model fitted the equilibrium data better than Freundlich and Dubinin-Radushkevich models and confirmed the surface homogeneity of adsorbent. The iron oxyhydroxide-coated rice straw (IOC-RS) was found to be effective for the removal of As(V) with 98.5% sorption efficiency at a concentration of <50 mg/L of As(V) solution, and thus maximum uptake capacity is ∼22 and 20 mg As(V)/g of IOC-RS at pH 4 and 6, respectively. The present study might provide new avenues to achieve the As concentrations required for drinking water recommended by the World Health Organization.

Natural biosorbents (garlic stem and horse chesnut shell) for removal of chromium(VI) from aqueous solutions.

The biosorption of Cr(VI) by the garlic stem (GS)-Allium sativum L. and horse chesnut shell (HCS)-Aesculus hippocastanum plant residues in a batch type reactor was studied in detail for the purpose of wastewater treatment. The influence of initial Cr(VI) concentration, time, and pH was investigated to optimize Cr(VI) removal from aqueous solutions and equilibrium isotherms and kinetic data. This influence was evaluated. The adsorption capacity of the GS and the HCS for Cr(VI) was determined with the Langmuir and Freundlich isotherm models, and the data was fitted to the Langmuir. The adsorption capacity of the GS and the HCS was found to be 103.09 and 142.85 mg/g of adsorbent from a solution containing 3000 ppm of Cr(VI), respectively. The GS's capacity was considerably lower than that of the HCS in its natural form. Gibbs free energy was spontaneous for all interactions, and the adsorption process exhibited exothermic enthalpy values. The HCS was shown to be a promising biosorbent for Cr(VI) removal from aqueous solutions.

Effects of different gas phases and gas bubbles on the nucleation kinetics.

In this study, the effects of different gas phases and gas bubbles on the Induction time were investigated. In the first step, the effects of different kinds of gases (N(2), Ar, dry air-N(2) and dry air-Ar) which are fed into solution-gas interphase and into the solution were determined. After determining the most effective gas upon the Induction time, the next step was to use this gas in the presence of the seed crystals, to specify variation in the Induction time. The experimental results show that gassing and the presence of seed crystal tend to shorten the Induction time as compared to the normal crystallization condition.

Methylene blue removal using nano-TiO2/MWCNT/Chitosan hydrogel composite beads in aqueous medium.

Dyestuff, one of the most hazardous compounds in terms of threats to people and the environment, is found in wastewater from industrial usage. The removal of Methylene Blue (MB) from a water-based medium has been studied by numerous researchers using a variety of adsorbents. To remove MB from aqueous solution, nano-TiO2/MWCNT/Chitosan hydrogel composite beads (n-TiO2/MWCNT/Cht) were developed in this study using a sol-gel method. This research discusses the characterisation of a new adsorbent substance using Infrared Spectroscopy (FT-IR) analysis and scanning electron microscopy (SEM). The optimal pH, adsorbent dosage, duration, and starting concentration were ascertained by analyzing the removal efficiencies of MB using the batch adsorption method. Adsorption behaviour at the equilibrium state has been investigated using a variety of adsorption isotherms, including Freundlich, Langmuir, and Dubinin-Radushkevich. The Langmuir adsorption isotherm has been useful to clarify adsorption behaviors. nTiO2-Cht/MWCNT had an adsorption capacity of 80.65 mg/g for MB. The pseudo-second-order kinetic model offered the best agreement to the experimental data for the adsorption of MB. Kinetic models of pseudo-first-order and pseudo-second-order were employed to explore the adsorption processes of MB on the n-TiO2/MWCNT/Cht. This study demonstrated the efficiency of n-TiO2/MWCNT/Cht for the removal of MB from a water-based solution.

In-situ growth of NiWO4 saw-blade-like nanostructures and their application in photo-electrochemical (PEC) immunosensor system designed for the detection of neuron-specific enolase.

This study describes the construction of highly-sensitive photo-electrochemical (PEC) immunosensor for the detection of neuron-specific enolase (NSE). The biosensing platform is comprised of photo-active NiWO4 nanostructures, in-situ-grown over a conductive substrate (indium tin oxide) using a low-temperature template-based co-precipitation approach. The discussed approach enables the formation of discrete, yet morphologically-analogous, nanostructures with complete coverage (pinhole-free) of the electrode surface. The in-situ-grown nanostructure possess dense population with sharp saw-blade like morphological features that can support substantial immobilisation of anti-NSE agent. The constructed platform demonstrated excellent photo-catalytic activity towards uric acid (UA) which served as the base for the Electrochemical -mechanism (EC) based PEC inhibition sensing. The detection of NSE, relied on its obstruction in analytical signal observed for the photo-oxidation of UA after binding to the electrode surface via protein-antibody interaction. The constructed PEC immunosensor exhibits signal sensitivity up to 0.12 ng mL-1 of NSE with excellent signal reproducibility and electrode replicability. Moreover, the constructed platform was successfully used for NSE determination in human serum samples.

Biogenic Silver Nanoparticles for Trace Colorimetric Sensing of Enzyme Disrupter Fungicide Vinclozolin.

We report a novel, simple, efficient, and green protocol for biogenic synthesis of silver nanoparticles (AgNPs) in aqueous solution using clove (Syzygium aromaticum) extract as a reducing and protecting agent. Ultraviolet-visible (UV-Vis) spectroscopy was employed to monitor the localized surface plasmon resonance (LSPR) band of clove extract-derived AgNPs prepared under various conditions. Fourier-transform infrared (FTIR) spectroscopy analysis provided information about the surface interaction of the clove extract with the AgNPs. Ultrahigh-resolution transmission electron microscopy (UHRTEM) results confirmed the formation of spherical, uniformly distributed clove extract-capped AgNPs with sizes in the range of 2-20 nm (average size: 14.4 ± 2 nm). Powder X-ray diffractometry analysis (PXRD) illustrated the formation of pure crystalline AgNPs. These AgNPs were tested as a colorimetric sensor to detect trace amounts of vinclozolin (VIN) by UV-Vis spectroscopy for the first time. The AgNP-based sensor demonstrated very sensitive and selective colorimetric detection of VIN, in the range of 2-16 µM (R2 = 0.997). The developed sensor was green, simple, sensitive, selective, economical, and novel, and could detect trace amounts of VIN with limit of detection (LOD) = 21 nM. Importantly, the sensor was successfully employed for the determination of VIN in real water samples collected from various areas in Turkey.

Biosorption of chromium(VI) ion from aqueous solutions using walnut, hazelnut and almond shell.

The potential to remove Cr(VI) ion from aqueous solutions through biosorption using, the shells of Walnut (WNS) (Juglans regia), Hazelnut (HNS) (Corylus avellana) and Almond (AS) (Prunus dulcis) was investigated in batch experiments. The equilibrium adsorption level was determined to be a function of the solution contact time and concentration. Kinetic experiments revealed that the dilute chromium solutions reached equilibrium within 100 min. The biosorptive capacity of the shells was dependent on the pH of the chromium solution, with pH 3.5 being optimal. Adsorption of Cr(VI) ion uptake is in all cases pH-dependent showing a maximum at equilibrium pH values between 2.0 and 3.5, depending on the biomaterial, that correspond to equilibrium pH values of 3.5 for (WNS), 3.5 for (HNS) and 3.2 for (AS). The adsorption data fit well with the Langmuir isotherm model. The sorption process conformed to the Langmuir isotherm with maximum Cr(VI) ion sorption capacities of 8.01, 8.28, and 3.40 mg/g for WNS, HNS and AS, respectively. Percentage removal by WNS, HNS and AS was 85.32, 88.46 and 55.00%, respectively at a concentration of 0.5 mM. HNS presented the highest adsorption capacities for the Cr(VI) ion.

Removal of Cr(VI) from aqueous solutions using modified red pine sawdust.

The adsorption of Cr(VI) from aqueous solutions on sawdust (SD), base extracted sawdust (BESD) and tartaric acid modified sawdust (TASD) of Turkish red pine tree (Pinus nigra), a timber industry waste, was studied at varying Cr(VI) concentrations, adsorbent dose, modifier concentration and pH. Batch adsorption studies have been carried out. Sawdust was collected from waste timber industry and modified with various amount of tartaric acid (TA) (0.1-1.5M). The batch sorption kinetics has been tested and the applicability of the Langmuir and Freundlich adsorption isotherms for the present system has been tested at 25+/-2 degrees C. Under observed test conditions, the equilibrium adsorption data fits the linear Freundlich isotherms. An initial pH of 3.0 was most favorable for Cr(VI) removal by all adsorbents. Maximum Cr(VI) was sequestered from the solution within 120 min after the beginning for every experiment. The experimental result inferred that chelation and ion exchange is one of the major adsorption mechanisms for binding metal ions to the SD. Percentage removal of Cr(VI) was maximum at the initial pH of 3.0 (87.7, 70.6 and 55.2% by TASD, BESD, and SD, respectively). Adsorption capacities range from 8.3 to 22.6 mg/g for SD samples.

Batch removal of chromium(VI) from aqueous solution by Turkish brown coals.

The ability of using low-rank Turkish brown coals (Ilgin: BC1, Beysehir: BC2, and Ermenek: BC3) to remove Cr(VI) from aqueous solutions was studied as a function of contact time, solution pH, temperature, concentration of metal solutions and amount of adsorbent. Their sorption properties were compared with the activated carbon from Chemviron (AQ-30). Adsorption of Cr(VI) uptake is in all cases pH-dependent showing a maximum at equilibrium pH values between 2.0 and 3.2, depending on the biomaterial, that correspond to initial pH values of 2.3 units for BC1, 3.0 units for BC2 and 3.2 units for BC3 and AQ-30. Batch equilibrium tests showed that the Cr(VI) removal was fitted with Freundlich isotherm and the adsorption reached equilibrium in 80 min. It was proceeding effectively into a short acid pH interval (2.0-3.2) where processes of Cr(VI) sorption are maximized. It was observed that the maximum adsorption capacity of 11.2 mM of Cr(VI)/g for Ilgin (BC1), 12.4 mM of Cr(VI)/g for Beysehir (BC2), 7.4 mM of Cr(VI)/g for Ermenek (BC3) and 6.8 mM of Cr(VI)/g for activated carbon (AQ-30) was achieved at pH of 3.0. The rise in temperature caused a slight decrease in the value of the equilibrium constant (K(c)) for the sorption of Cr(VI) ion. The Cr(VI) sorption capacities of Beysehir and Ilgin brown coals were the same. Ermenek brown coals and activated carbon (AQ-30) showed a similar sorption capacity.

Sorption of Cr(III) onto chelating b-DAEG-sporopollenin and CEP-sporopollenin resins.

In the present study, the removal of Cr(III) from aqueous solution was studied using a new chelate-resins (b-DAEG-sporopollenin and CEP-sporopollenin). Mechanisms including ion exchange, complexation and adsorption to the surface are possible in the sorption process. Adsorption analysis results obtained at various concentrations of Cr(III) showed that the adsorption pattern on the resin followed a Langmuir isotherm. Langmuir constant Gamma max and k for Cr(III) were found as 1.23, 84.84 mmol/g for b-DAEG-sporopollenin, 133.33, 10.39 mmol/g for CEP-sporopollenin at 20 +/- 1 degrees C, respectively. In addition, kinetic and thermodynamic parameters such as enthalpy (DeltaH0), free energy (DeltaG0) and entropy (DeltaS0) were calculated and these values show that adsorption of Cr(III) on b-DAEG-sporopollenin and CEP-sporopollenin was an exothermic process and the process of adsorption was favored at high temperatures. Maximum Cr(III) removal was observed near a pH of 6.

Ion-exchange of Pb2+, Cu2+, Zn2+, Cd2+, and Ni2+ ions from aqueous solution by Lewatit CNP 80.

Removal of trace amounts of heavy metals can be achieved by means of selective ion-exchange processes. The newly developed resins offered a high resin capacity and faster sorption kinetics for the metal ions such as Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+) ions. In the present study, the removal of Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+) ions from aqueous solutions was investigated. Experimental investigations were undertaken using the ion-exchange resin Lewatit CNP 80 (weakly acidic) and were compared with Lewatit TP 207 (weakly acidic and chelating). The optimum pH range for the ion-exchange of the above mentioned metal ions on Lewatit CNP 80 and Lewatit TP 207 were 7.0-9.0 and 4.5-5.5, respectively. The influence of pH, contact time, metal concentration and amount of ion-exchanger on the removal process was investigated. For investigations of the exchange equilibrium, different amounts of resin were contacted with a fixed volume of Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+) ion containing solution. The obtained sorption affinity sequence in the presented work was Ni(2+)>Cu(2+)>Cd(2+)>Zn(2+)>Pb(2+). The metal ion concentrations were measured by AAS methods. The distribution coefficient values for metal ions of 10(-3)M initial concentration at 0.1mol/L ionic strength show that the Lewatit CNP 80 was more selective for Ni(2+), Cu(2+) than it was for Cd(2+), Zn(2+) and Pb(2+). Langmuir isotherm was applicable to the ion-exchange process and its contents were calculated. The uptake of metal ions by the ion-exchange resins was reversible and thus has good potential for the removal of Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+) from aqueous solutions. The amount of sorbed metal ion per gram dry were calculated as 4.1, 4.6, 4.7, 4.8, and 4.7mequiv./g dry resin for Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+), respectively. Selectivity increased in the series: Cd(2+)>Pb(2+)>Cu(2+)>Ni(2+)>Zn(2+). The results obtained showed that Lewatit CNP 80 weakly acidic resin had shown better performance than Lewatit TP 207 resin for the removal of metals. The change of the ionic strength of the solution exerts a slight influence on the removal of Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+). The presence of low ionic strength or low concentration of NaNO(3) does not have a significant effect on the ion-exchange of these metals by the resins. We conclude that Lewatit CNP 80 can be used for the efficient removal of Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+) from aqueous solutions.

The study of various parameters affecting the ion exchange of Cu2+, Zn2+, Ni2+, Cd2+, and Pb2+ from aqueous solution on Dowex 50W synthetic resin.

A gel resin containing sulfonate groups (Dowex 50W) was investigated for its sorption properties towards copper, zinc, nickel, cadmium and lead metal ions. The use of selective ion exchange to recover metals from aqueous solution has been studied. The ion exchange behavior of five metals on Dowex 50W, depending on pH, temperature, and contact time and adsorbate amount was studied. Experimental measurements have been made on the batch sorption of toxic metals from aqueous solutions using cation exchanger Dowex 50W. The maximum recoveries (about 97%) Cu(2+), Zn(2+), Ni(2+), Cd(2+) and (about 80%) Pb(2+) were found at pH ranges 8-9. The amount of sorbed metal ion was calculated as 4.1, 4.6, 4.7, 4.8, and 4.7mequiv./gram dry resin for Pb(2+), Cu(2+), Zn(2+), Cd(2+), and Ni(2+), respectively. The precision of the method was examined at under optimum conditions. Selectivity increased in the series: Pb>Cd>Cu>Zn>Ni. It has been observed that, selectivity of the -SO(3)H group of the resin increases with atomic number, valance, degree of ionization of the exchanged metals. The equilibrium ion exchange capacity of resin for metal ions was measured and explored by using Freundlich and Langmuir isotherms. Langmuir type sorption isotherm was suitable for equilibrium studies.

Removal of chromium(III) from aqueous solutions using Lewatit S 100: the effect of pH, time, metal concentration and temperature.

The removal of the Cr(III) ion from aqueous solutions with the Lewatit S 100 ion-exchange resin is described; and the performance of this resin was compared with Chelex-100 resin. The effect of adsorbent dose, initial metal concentration, contact time, pH and temperature on the removal of Cr(III) was investigated. Lewatit S 100 shows a remarkable increase in sorption capacity for Cr(III). The Batch ion-exchange process was relatively fast; and it reached equilibrium after about 150 min of contact. The ion-exchange process, which is pH dependent show maximum removal of Cr(III) in the pH range 2.8-4.0 for an initial Cr(III) concentration of 1.0 x 10(-3)M. The equilibrium constants were 36.67 at pH value 3.5 for Lewatit S 100 and 6.64 at pH value 4.5 for Chelex-100 resin. Both of the resins had high-bonding constants. The equilibrium related to their ion-exchange capacity and the amount of the ion exchange was obtained by using the plots of the Langmuir adsorption isotherm. It was observed that the maximum ion-exchange capacity of 0.39 mmol of Cr(III)/g for Lewatit S 100 and 0.29 mmol of Cr(III)/g for Chelex-100 was achieved at optimum pH values of 3.5 and 4.5, respectively. The thermodynamic equilibrium constant and the Gibbs free energy flow were calculated for each system. The ion exchange of Cr(III) on these cation-exchange resins followed first-order reversible kinetics. The intra-particle diffusion of Cr(III) on ion-exchange resin represented the rate-limiting step. The rise in temperature caused a slight increase in the value of the equilibrium constant (K(c)) for the sorption of Cr(III) ion for both resins.

Adsorption of Cu(II), Zn(II), Ni(II), Pb(II), and Cd(II) from aqueous solution on Amberlite IR-120 synthetic resin.

The adsorption of copper(II), zinc(II), nickel(II), lead(II), and cadmium(II) on Amberlite IR-120 synthetic sulfonated resin has been studied at different pH and temperatures by batch process. The effects of parameters such as amount of resin, resin contact time, pH, and temperature on the ion exchange separation have been investigated. For the determination of the adsorption behavior of the resin, the adsorption isotherms of metal ions have also been studied. The concentrations of metal ions have been measured by batch techniques and with AAS analysis. Adsorption analysis results obtained at various concentrations showed that the adsorption pattern on the resin followed Freundlich isotherms. Here we report the method that is applied for the sorption/separation of some toxic metals from their solutions.

Removal of Cr(VI) from aqueous solution by two Lewatit-anion exchange resins.

The sorption of hexavalent chromium, Cr(VI), from aqueous solutions on macroporous resins containing tertiary amine groups (Lewatit MP 62 and Lewatit M 610) was studied at varying Cr(VI) concentrations, adsorbent dose, pH, contact time and temperatures. The concentration of chromium in aqueous solution was determined by inductively coupled plasma spectrometry (ICP-AES). Batch shaking sorption experiments were carried out to evaluate the performance of Lewatit MP 62 and Lewatit M 610 anion exchange resins in the removal of Cr(VI) from aqueous solutions. The ion-exchange process, which is pH dependent, shows maximum removal of Cr(VI) in the pH range 2-6 for an initial Cr(VI) concentration of 100 ppm. The sorption increases with the decrease in pH and slightly decreases with the increase in temperature. Both ion exchangers had high bonding constants with Lewatit M 610 showing stronger binding. It was observed that the maximum adsorption capacity of 0.40 mmol of Cr(VI)/g for Lewatit MP 62 and 0.41 mmol of Cr(VI)/g for Lewatit M 610 was achieved at pH of 5.0. The thermodynamic parameters (free energy change, DeltaG degrees ; enthalpy change, DeltaS degrees ; and entropy change, DeltaH degrees ) for the sorption have been evaluated. The rise in temperature caused a slight decrease in the value of the equilibrium constant (Kc) for the sorption of Cr(VI) ion. The sorption of Cr(VI) on the resin was rapid during the first 15 min and equilibrium was found to be attained within 30 min. The sorption of Cr(VI) onto the resins followed reversible first-order rate kinetics. Such ion exchange resins can be used for the efficient removal of chromium from water and wastewater.

Utilization of barley straws as biosorbents for Cu2+ and Pb2+ ions.

The potential to remove Cu(2+) and Pb(2+) ion from aqueous solutions through biosorption using barley straw (BS) was investigated in batch experiments. The main parameters influencing Cu(2+) and Pb(2+) ion sorption on BS were: initial metal ion concentration, amount of adsorbent, contact time and pH value of solution. The influences of initial Cu(2+) and Pb(2+) ion concentration (0.1-1mM), pH (2-9), contact time (10-240 min) and adsorbent amount (0.1-1.0 g) have been reported. Equilibrium isotherms have been measured and modelled. The percent adsorption of Cu(2+) and Pb(2+) ions increased with an increase in pH and dosage of treated BS. The biosorptive capacity of the BS was dependent on the pH of Cu(2+) and Pb(2+) ion solution. Adsorption of Cu(2+) and Pb(2+) ion was in all cases pH dependent showing a maximum at equilibrium pH value at 6.0. The equilibrium sorption capacities of Cu(2+) and Pb(2+) after 2h were 4.64 mg/g and 23.20mg/g for BS, respectively. The adsorption data fit well with the Langmuir isotherm model and the experimental result inferred that complexation on surface, adsorption (chemisorption) and ion exchange is one of the major adsorption mechanisms for binding Cu(2+) and Pb(2+) ion to the sorbents.