Comparison of pyrochar, hydrochar and lignite as additive in anaerobic digestion and NH4+ adsorbent.

The impact of pyrochar, hydrochar and lignite addition on anaerobic digestion of food waste was investigated with and without ammonia inhibition under batch conditions. Furthermore, ammonium adsorption capacities of the chars were investigated. To determine anaerobic degradation of char, reference samples containing inoculum and char were analyzed, indicating a significant degradation of hydrochar. Depending on the evaluation method, the increase in methane yield due to hydrochar addition varied between no statistically significant difference and +14 %. No significant impact due to the addition of 5 g/l pyrochar and lignite on AD was found. NH4+ adsorption capacities showed a significantly higher net adsorption capacity of lignite (1.58mgNH4+/gL), compared to pyrochar (0.63mgNH4+/gPC). A negative NH4+ adsorption capacity (-0.51 mgNH4+/gHC) was found for hydrochar. A high H/C-ratio, O/C-ratio and cation exchange capacity of hydrochar and lignite indicate many functional groups and low chemical stability, enabling an increased interaction between NH4+ and char.

Model studies on CO oxidation catalyst systems: titania and gold nanoparticles.

The peculiar catalytic activity of Au-supported titanium dioxide surfaces in the CO oxidation reaction has been a focus of interest for more than twenty years. Herein, recent data concerning preparation and structural characterisation of planar catalyst model systems consisting of single-crystalline titania and/or gold nanoparticles deposited thereon is presented and reviewed. We first expand on the deposition and growth of TiO(2) films on selected metal host surfaces and then consider the deposition of Au nanoparticles on these surfaces, including information on their geometric and electronic structures. The second issue is the interaction of these materials with carbon monoxide (one of the essential ingredients of the CO oxidation reaction) which serves as a probe molecule and monitor of the chemical activity of the model catalyst samples. Concerted efforts relating the structural and chemical properties of the respective binary materials (titania support plus deposited gold) can help to tackle and finally resolve the still open problems concerning the high activity of Au-TiO(2) catalysts in the CO oxidation reaction.

Influence of iron precipitated condition and light intensity on microalgae activated sludge based wastewater remediation.

The indigenous microalgae-activated sludge (MAAS) process during remediation of municipal wastewater was investigated by studying the influence of iron flocculation step and light intensity. In addition, availability of total phosphorous (P) and photosynthetic activity was examined in fed-batch and batch mode under northern climatic conditions and limited lighting. This was followed by a semi-continuous operation with 4 d of hydraulic retention time and mean cell residence time of 6.75 d in a photo-bioreactor (PBR) with varying P availability. The fed-batch condition showed that P concentrations of 3-4 mg L-1 were effective for photosynthetic chl. a development in iron flocculated conditions. In the PBR, the oxygen evolution rate increased with increase in the concentration of MAAS (from 258 to 573 mg TSS L-1) at higher surface photosynthetic active radiation (250 and 500 µmol m-2 s-1). Additionally, the rate approached a saturation phase at low MAAS (110 mg L-1) with higher light intensities. Semi-continuous operation with luxury P uptake and effective P condition showed stable average total nitrogen removal of 88 and 92% respectively, with residual concentrations of 3.77 and 2.21 mg L-1. The corresponding average P removal was 68 and 59% with residual concentrations of 2.32 and 1.75 mg L-1. The semi-continuous operation produced a rapidly settleable MAAS under iron flocculated condition with a settling velocity of 92-106 m h-1 and sludge volume index of 31-43 ml g-1 in the studied cases.

Using slaughterhouse waste in a biochemical-based biorefinery - results from pilot scale tests.

A novel biorefinery concept was piloted using protein-rich slaughterhouse waste, chicken manure and straw as feedstocks. The basic idea was to provide a proof of concept for the production of platform chemicals and biofuels from organic waste materials at non-septic conditions. The desired biochemical routes were 2,3-butanediol and acetone-butanol fermentation. The results showed that hydrolysis resulted only in low amounts of easily degradable carbohydrates. However, amino acids released from the protein-rich slaughterhouse waste were utilized and fermented by the bacteria in the process. Product formation was directed towards acidogenic compounds rather than solventogenic products due to increasing pH-value affected by ammonia release during amino acid fermentation. Hence, the process was not effective for 2,3-butanediol production, whereas butyrate, propionate, γ-aminobutyrate and valerate were predominantly produced. This offered fast means for converting tedious protein-rich waste mixtures into utilizable chemical goods. Furthermore, the residual liquid from the bioreactor showed significantly higher biogas production potential than the corresponding substrates. The combination of the biorefinery approach to produce chemicals and biofuels with anaerobic digestion of the residues to recover energy in form of methane and nutrients that can be utilized for animal feed production could be a feasible concept for organic waste utilization.

Influence of hydraulic retention time on indigenous microalgae and activated sludge process.

Integration of the microalgae and activated sludge (MAAS) process in municipal wastewater treatment and biogas production from recovered MAAS was investigated by studying the hydraulic retention time (HRT) of semi-continuous photo-bioreactors. An average total nitrogen (TN) removal efficiency (RE) of maximum 81.5 ± 5.1 and 64.6 ± 16.2% was achieved at 6 and 4 days HRT. RE of total phosphorous (TP) increased slightly at 6 days (80 ± 12%) HRT and stabilized at 4 days (56 ± 5%) and 2 days (55.5 ± 5.5%) HRT due to the fluctuations in COD and N/P mass ratio of the periodic wastewater. COD and organic carbon were removed efficiently and a rapidly settleable MAAS with a sludge volume index (SVI_10) of less than 117 mL g(-1) was observed at all HRTs. The anaerobic digestion of the untreated MAAS showed a higher biogas yield of 349 ± 10 mL g VS(-1) with 2 days HRT due to a low solids retention time (SRT). Thermal pretreatment of the MAAS (120 °C, 120 min) did not show any improvement with biogas production at 6 days (269 ± 3 (untreated) and 266 ± 16 (treated) mL gVS(-1)), 4 days (258 ± 11(untreated) and 263 ± 10 (treated) mL gVS(-1)) and 2 days (308 ± 19 mL (treated) gVS(-1)) HRT. Hence, the biogas potential tests showed that the untreated MAAS was a feasible substrate for biogas production. Results from this proof of concept support the application of MAAS in wastewater treatment for Swedish conditions to reduce aeration, precipitation chemicals and CO2 emissions.

Anaerobic co-digestion of the marine microalga Nannochloropsis salina with energy crops.

Anaerobic co-digestion of corn silage with the marine microalga Nannochloropsis salina was investigated under batch and semi-continuous conditions. Under batch conditions process stability and biogas yields significantly increased by microalgae addition. During semi-continuous long-term experiments anaerobic digestion was stable in corn silage mono- and co-digestion with the algal biomass for more than 200 days. At higher organic loading rates (4.7 kg volatile solids m(-3)d(-1)) inhibition and finally process failure occurred in corn silage mono-digestion, whereas acid and methane formation remained balanced in co-digestion. The positive influences in co-digestion can be attributed to an adjusted carbon to nitrogen ratio, enhanced alkalinity, essential trace elements and a balanced nutrient composition. The results suggest that N. salina biomass is a suitable feedstock for anaerobic co-digestion of energy crops, especially for regions with manure scarcity. Enhanced process stability may result in higher organic loading rates or lower digester volumes.

Effects of thermal pretreatment on anaerobic digestion of Nannochloropsis salina biomass.

The marine microalga Nannochloropsis salina was investigated as feedstock for anaerobic digestion under batch and semi-continuous conditions for the first time. Biodegradability and methane yield were low under both digestion conditions. Thermal pretreatment prior to anaerobic digestion significantly increased the methane yield from 0.2 to 0.57 m(3) kg VS(-1) under batch conditions and from 0.13 to 0.27 m(3) kg VS(-1) in semi-continuous digestion. Still, the methane yield was limited with semi-continuous feeding due to volatile fatty acid (VFA) accumulation in the digester caused by high ammonium and salt concentrations in the feedstock. Despite VFA accumulation adaption of the microorganisms to the changing conditions and high buffer capacity resulted in steady methane production. A first energy balance considering the required heat for thermal pretreatment revealed significant benefit from the pretreatment. Conversely, the high energy demand for dewatering algal cultures is one major bottleneck for industrial-scale processing of microalgae.