A stable atmospheric-pressure plasma for extreme-temperature synthesis.

Plasmas can generate ultra-high-temperature reactive environments that can be used for the synthesis and processing of a wide range of materials1,2. However, the limited volume, instability and non-uniformity of plasmas have made it challenging to scalably manufacture bulk, high-temperature materials3-8. Here we present a plasma set-up consisting of a pair of carbon-fibre-tip-enhanced electrodes that enable the generation of a uniform, ultra-high temperature and stable plasma (up to 8,000 K) at atmospheric pressure using a combination of vertically oriented long and short carbon fibres. The long carbon fibres initiate the plasma by micro-spark discharge at a low breakdown voltage, whereas the short carbon fibres coalesce the discharge into a volumetric and stable ultra-high-temperature plasma. As a proof of concept, we used this process to synthesize various extreme materials in seconds, including ultra-high-temperature ceramics (for example, hafnium carbonitride) and refractory metal alloys. Moreover, the carbon-fibre electrodes are highly flexible and can be shaped for various syntheses. This simple and practical plasma technology may help overcome the challenges in high-temperature synthesis and enable large-scale electrified plasma manufacturing powered by renewable electricity.

Theoretical model of external spinal cord stimulation.

In this paper, a simple theoretical model of the excitation of action potentials of multiple motor pools by stimulating current pulses over the lumbosacral regions of the spinal cord is presented. The present model is consistent with known experimental data.

Single-shot nanosecond-resolution multiframe passive imaging by multiplexed structured image capture.

The Multiplexed Structured Image Capture (MUSIC) technique is used to demonstrate single-shot multiframe passive imaging, with a nanosecond difference between the resulting images. This technique uses modulation of light from a scene before imaging, in order to encode the target's temporal evolution into spatial frequency shifts, each of which corresponds to a unique time and results in individual and distinct snapshots. The resulting images correspond to different effective imaging gate times, because of the optical path delays. Computer processing of the multiplexed single-shot image recovers the nanosecond-resolution evolution. The MUSIC technique is used to demonstrate imaging of a laser-induced plasma. Simultaneous single-shot measurements of electron numbers by coherent microwave scattering were obtained and showed good agreement with MUSIC characterization. The MUSIC technique demonstrates spatial modulation of images used for passive imaging. This allows multiple frames to be stacked into a single image. This method could also pave the way for real-time imaging and characterization of ultrafast processes and visualization, as well as general tracking of fast objects.

New diagnostic methods for laser plasma- and microwave-enhanced combustion.

The study of pulsed laser- and microwave-induced plasma interactions with atmospheric and higher pressure combusting gases requires rapid diagnostic methods that are capable of determining the mechanisms by which these interactions are taking place. New rapid diagnostics are presented here extending the capabilities of Rayleigh and Thomson scattering and resonance-enhanced multi-photon ionization (REMPI) detection and introducing femtosecond laser-induced velocity and temperature profile imaging. Spectrally filtered Rayleigh scattering provides a method for the planar imaging of temperature fields for constant pressure interactions and line imaging of velocity, temperature and density profiles. Depolarization of Rayleigh scattering provides a measure of the dissociation fraction, and multi-wavelength line imaging enables the separation of Thomson scattering from Rayleigh scattering. Radar REMPI takes advantage of high-frequency microwave scattering from the region of laser-selected species ionization to extend REMPI to atmospheric pressures and implement it as a stand-off detection method for atomic and molecular species in combusting environments. Femtosecond laser electronic excitation tagging (FLEET) generates highly excited molecular species and dissociation through the focal zone of the laser. The prompt fluorescence from excited molecular species yields temperature profiles, and the delayed fluorescence from recombining atomic fragments yields velocity profiles.

Enhancements of electric field and afterglow of non-equilibrium plasma by Pb(ZrxTi1-x)O3 ferroelectric electrode.

Manipulating surface charge, electric field, and plasma afterglow in a non-equilibrium plasma is critical to control plasma-surface interaction for plasma catalysis and manufacturing. Here, we show enhancements of surface charge, electric field during breakdown, and afterglow by ferroelectric barrier discharge. The results show that the ferroelectrics manifest spontaneous electric polarization to increase the surface charge by two orders of magnitude compared to discharge with an alumina barrier. Time-resolved in-situ electric field measurements reveal that the fast polarization of ferroelectrics enhances the electric field during the breakdown in streamer discharge and doubles the electric field compared to the dielectric barrier discharge. Moreover, due to the existence of surface charge, the ferroelectric electrode extends the afterglow time and makes discharge sustained longer when alternating the external electric field polarity. The present results show that ferroelectric barrier discharge offers a promising technique to tune plasma properties for efficient plasma catalysis and electrified manufacturing.

The possibility of anesthesia stimulated by a train of current pulses.

This study considers a simple theoretical model of blocking the passage of signals (action potentials) from sensory neurons, thereby affecting anesthesia without the use of anesthetics as a result of a sequence of unipolar current pulses generated by an external source. The proposed model allows the selection of parameters and the required frequency of the repetition of current pulses for the possible implementation of anesthesia, depending on the electrical characteristics of the skin and the conductivity of the saline solution in which the myelinated nerve fibers are located.

Experimental and numerical analysis of narrowband coherent Rayleigh-Brillouin scattering in atomic and molecular species.

Coherent Rayleigh-Brillouin scattering (CRBS) line shapes generated from all narrow-band pump experiment, Direct Simulation Monte-Carlo (DSMC) approach, and published kinetic line shape models are presented for argon, molecular nitrogen, and methane at 300 & 500 K and 1 atm. The kinetic line shape models require uncertain gas properties, such as bulk viscosity, and assume linearization of the kinetic equations from low intensities (<1 x 10¹5 W/m²) operating in the perturbative regime. DSMC, a statistical approach to the Boltzmann equation, requires only basic gas parameters available in literature and simulates the forcing function from first principles without assumptions on laser intensity. The narrow band experiments show similar results to broadband experiments and validate the use of DSMC for the prediction of CRBS line shapes.

Ionization rate and plasma dynamics at 3.9 micron femtosecond photoionization of air.

The introduction of mid-IR optical parametric chirped pulse amplifiers has catalyzed interest in multimillijoule, infrared femtosecond pulse-based filamentation. As tunneling ionization is a fundamental first stage in these high-intensity laser-matter interactions, characterizing the process is critical to understand derivative topical studies on femtosecond filamentation and self-focusing. Here, we report direct nonintrusive measurements of total electron count and electron number densities generated at 3.9 µm femtosecond midinfrared tunneling ionization of atmospheric air using constructive-elastic microwave scattering. Subsequently, we determine photoionization rates to be in the range 5.0×10^{8}-6.1×10^{9}s^{-1} for radiation intensities of 1.3×10^{13}-1.9×10^{14}W/cm^{2}, respectively. The proposed approach paves the wave to precisely tabulate photoionization rates in mid-IR for a broad range of intensities and gas types and to study plasma dynamics at mid-IR filamentation.

Strong local-field effect on the dynamics of a dilute atomic gas irradiated by two counterpropagating optical fields: beyond standard optical lattices.

We study a recent experiment [K. Li et al., Phys. Rev. Lett. 101, 250401 (2008)] on diffracting a Bose-Einstein condensate by two counterpropagating optical fields. Including the local-field effect, we explain the asymmetric momentum distribution and self-imaging of the Bose-Einstein condensate self-consistently. Moreover, we find that the two counterpropagating optical fields could not produce a perfect optical lattice, which is actually deformed by the local-field effect. Our work implies that the local-field effect could be essential for getting a better quantitative analysis of other optical lattice experiments. In particular, the intensity imbalance of the two optical fields could act as a new means to tailor both cold atom dynamics and light propagation.

Two-color scattering for the measurement of neutrals at the edge of fusion devices.

Laser two-color scattering (TCS) is proposed to detect the neutral species in the edge of fusion devices, namely, tokamaks. TCS uses two wavelengths to probe both the laser Rayleigh scattering and Thomson scattering of the neutral-electron bath, with emphasis on neutral density measurements such as that of hydrogen and deuterium. Modeling of the Rayleigh scattering of tokamak neutral species under various plasma conditions (electron density and temperature) shows that, with an appropriate filtering of the Thomson signal and by going to ultraviolet-region wavelengths, identification of the Rayleigh signal can be achieved. Photon count and signal fractions are calculated in two test cases, one in the midplane region of the National Spherical Torus Experiment and one in the divertor region of DIII-D. An uncertainty analysis and discussion of the feasibility of the TCS diagnostic is also presented.

Thomson and collisional regimes of in-phase coherent microwave scattering off gaseous microplasmas.

The total number of electrons in a classical microplasma can be non-intrusively measured through elastic in-phase coherent microwave scattering (CMS). Here, we establish a theoretical basis for the CMS diagnostic technique with an emphasis on Thomson and collisional scattering in short, thin unmagnetized plasma media. Experimental validation of the diagnostic is subsequently performed via linearly polarized, variable frequency (10.5-12 GHz) microwave scattering off laser induced 1-760 Torr air-based microplasmas (287.5 nm O2 resonant photoionization by ~ 5 ns, < 3 mJ pulses) with diverse ionization and collisional features. Namely, conducted studies include a verification of short-dipole-like radiation behavior, plasma volume imaging via ICCD photography, and measurements of relative phases, total scattering cross-sections, and total number of electrons [Formula: see text] in the generated plasma filaments following absolute calibration using a dielectric scattering sample. Findings of the paper suggest an ideality of CMS in the Thomson "free-electron" regime-where a detailed knowledge of plasma and collisional properties (which are often difficult to accurately characterize due to the potential influence of inhomogeneities, local temperatures and densities, present species, and so on) is unnecessary to extract [Formula: see text] from the scattered signal. The Thomson scattering regime of microwaves is further experimentally verified via measurements of the relative phase between the incident electric field and electron displacement.

Kinetics Model of Femtosecond Laser Ionization in Nitrogen and Comparison to Experiment.

A zero-dimensional kinetics simulation of femtosecond laser ionization in nitrogen is proposed that includes fast gas heating effects, electron scattering (elastic and inelastic) rate coefficients from BOLSIG+ and photoionization based on filamentation theory. Key rate coefficients possessing significant uncertainty are tuned (within the range of variation found in literature) to reproduce the time-varying signal acquired by a bandpass-filtered photomultiplier tube with good agreement up to several hundred nanoseconds. Separate spectral measurements calibrate the relative strength of signal components. Derived equations relate the model to experimental measurements in absolute units. Reactions contributing to the rate of change of important species are displayed in terms of absolute rate and relative fraction. In general, decreasing the gas density lengthens the duration of early reactions and delays the start of later reactions. The model agrees with data taken in a variable temperature and pressure free jet by an intensified camera. Results demonstrate that initial signal depends primarily on gas density and secondarily on gas temperature. The optimal (maximum) initial signal occurs at a gas density below atmospheric. Decreases in gas density alter the evolution of excited-state populations, postponing the peak (while reducing its value) and slowing the rate of decay. For the optimal case, populations are favorably shifted in time with respect to the gate delay (and width) to boost the signal. Reductions in gas temperature generally enhance initial signal due to elevated dissociative recombination of cluster ions (along with excited-state coupling from quenching and energy pooling).

Average electron temperature estimation of streamer discharge in ambient air.

The electron temperature of small streamer plasmas with low ionization degree is difficult to measure using existing diagnostic technologies such as Langmuir probe and laser Thomson scattering. In this report, we introduce a method of average electron temperature estimation based on the electron continuity equation. The equation includes a temporal derivative of electron density as the summation of diffusion current, drift current, and electron gain/loss events. In the considered example, the electron density is measured using the Rayleigh scattering while the currents and the rate coefficients of those events are functions of the electric field, electron collision frequency, and electron temperature. Therefore, once the electric field and collision frequency are either measured or estimated, the only unknown in the equation is the average electron temperature which can be solved. It was estimated that electron temperature in the streamer peaks at about 3.9 eV for the given example.

In situ Characterization of Nanoparticles Using Rayleigh Scattering.

We report a theoretical analysis showing that Rayleigh scattering could be used to monitor the growth of nanoparticles under arc discharge conditions. We compute the Rayleigh scattering cross sections of the nanoparticles by combining light scattering theory for gas-particle mixtures with calculations of the dynamic electronic polarizability of the nanoparticles. We find that the resolution of the Rayleigh scattering probe is adequate to detect nanoparticles as small as C60 at the expected concentrations of synthesis conditions in the arc periphery. Larger asymmetric nanoparticles would yield brighter signals, making possible to follow the evolution of the growing nanoparticle population from the evolution of the scattered intensity. Observable spectral features include characteristic resonant behaviour, shape-dependent depolarization ratio, and mass-dependent line shape. Direct observation of nanoparticles in the early stages of growth with unobtrusive laser probes should give insight on the particle formation mechanisms and may lead to better-controlled synthesis protocols.

Coherent microwave rayleigh scattering from resonance-enhanced multiphoton ionization in argon.

Multiphoton ionization and electron recombination processes are studied in argon using coherent microwave Rayleigh scattering from a localized, resonance-enhanced multiphoton ionization produced plasma. A time dependent one-dimensional plasma dynamic model is developed to predict the time evolution of the microwave scattering from the plasma. Experimental results of the argon ionization spectrum and electron recombination rates are in good agreement with the model predictions.

Guiding radar signals by arrays of laser-induced filaments: finite-difference analysis.

Circular arrays of plasma filaments induced by femtosecond laser pulses in atmospheric air are shown to support guided modes of electromagnetic radiation in the centimeter and millimeter wavelength range. With the refractive index of laser-induced filaments being lower than the refractive index of nonionized air, arrays of such filaments can serve as a structured waveguide cladding, providing an index guiding of radar signals in a nonionized gas region. In spite of attenuation of radar radiation induced by plasma absorption, filament-array waveguides are shown to enhance radar signal transmission relative to freely propagating radar beams.

Coherent Rayleigh-Brillouin scattering.

Coherent Rayleigh-Brillouin scattering in gases has been studied experimentally for the first time in the kinetic regime and shown to give line shapes that differ significantly from the spontaneous Rayleigh-Brillouin scattering. A kinetic model was developed to obtain an analytic solution of the line shape for monatomic gases, and good agreement with the experimental data was achieved.

Temperature measurements by coherent Rayleigh scattering.

We demonstrate, for the first time to our knowledge, the utility of coherent Rayleigh scattering (CRS) for temperature measurements in low-density gases and weakly ionized plasmas by measuring the translational temperature of neutral argon in a glow discharge. By analysis of the near-Gaussian spectral profile of the CRS signal, we determine temperatures with an uncertainty of