Spectral filtering effect on the ultrafast mid-infrared Er3+-doped ZBLAN fiber laser.

We investigate the spectral filtering effect on the mid-infrared ultrafast Er3+-doped ZBLAN fiber laser based on nonlinear polarization evolution (NPE). A broad wavelength tuning range from 2720 nm to 2800 nm is achieved using a diffraction grating as the narrowband filter. Furthermore, numerical simulations are also carried out so that, by inserting a highly nonlinear fiber combined with an appropriate spectral filter in the laser system, a 329 nm ultra-broadband spectrum with a Fourier transform limit pulse as short as 47 fs can be achieved. Our results are conducive to understanding the spectral filtering effect on the lasing performance of mid-infrared ultrafast fiber lasers.

One-Photon Solutions to the Multiqubit Multimode Quantum Rabi Model for Fast W-State Generation.

General solutions to the quantum Rabi model involve subspaces with an unbounded number of photons. However, for the multiqubit multimode case, we find special solutions with at most one photon for an arbitrary number of qubits and photon modes. Such solutions exist for arbitrary single qubit-photon coupling strength with constant eigenenergy, while still being qubit-photon entangled states. Taking advantage of their peculiarities and the reach of the ultrastrong coupling regime, we propose an adiabatic scheme for the fast and deterministic generation of a two-qubit Bell state and arbitrary single-photon multimode W states with nonadiabatic error less than 1%. Finally, we propose a superconducting circuit design to catch and release the W states, and shows the experimental feasibility of the multimode multiqubit quantum Rabi model.

One-pot synthesized Bi2Te3/graphene for a self-powered photoelectrochemical-type photodetector.

Bismuth telluride (Bi2Te3) is a typical topological insulator, which possesses a narrow band gap and exhibits fascinating performance in the photodetector field. In this work, we fabricated a Bi2Te3/graphene heterostructure via a facile one-pot hydrothermal method. The as-prepared composites were used as the electrode materials for the photoelectrochemical (PEC)-type photodetector. From the results of PEC tests, we obviously found that the Bi2Te3/graphene heterostructure offers a remarkable improvement in photoresponse compared to that of sole Bi2Te3, and effectively demonstrates effective photocarrier generation and transfer at the interface between the graphene and Bi2Te3, which can enhance the properties of the photoresponse. Moreover, owing to the self-powered ability of the PEC-type photodetector, it can work under the bias potential of 0 V and exhibits a prominent photoresponse which can reach 2.2 mA W-1. Also, the photocurrent density of the prepared Bi2Te3/graphene heterostructure-based photodetector can almost linearly rise with the increased irradiation power density. Even if the light intensity was reduced to 40 mW cm-2, the photocurrent density could also reach 67 µA cm-2, which ensures the photodetection ability of the as-prepared Bi2Te3/graphene under low light intensity. The excellent performance of a Bi2Te3/graphene heterostructure for a PEC-type photodetector holds great promise in the field of photoelectric detection.

Large object distance and super-resolution graded-index photonic crystal flat lens.

In order to realize super-resolution imaging of point source at any positions within a large object distance range, a graded-index equivalent medium (GEM) flat lens, which can break through the object distance limit d (d is the lens thickness), is analyzed by negative refraction. Based on this analysis, graded-index photonic crystal (GPC) flat lens with a large object distance is designed. Its imaging resolution can reach up to 0.4λ at the maximum object distance of 5d, which breaks through the diffraction limit.

Gold nanostars as a Q-switcher for the mid-infrared erbium-doped fluoride fiber laser.

We demonstrated passively Q-switched mid-infrared (mid-IR) erbium-doped fiber lasers by using gold nanostars (GNSs) as the Q-switcher. The nonlinear optical responses of the GNSs synthesized via the seed-mediated method have been characterized via a Z-scan technique, and the modulation depth and saturation intensity of the GNSs are measured to be 25% and 15.75 kW/cm2, respectively. The Q-switched fiber laser can deliver a maximum average power of 454 mW with corresponding pulse energy of 3.6 µJ and pulse duration of 536 ns at a repetition rate of 125 kHz under the incident pump power 3.5 W. To the best of our knowledge, this is the first Letter that reports that the GNSs can act as a Q-switcher for the mid-IR erbium-doped ZBLAN fiber lasers. This Letter can deepen the understanding of the nonlinear optical behavior of the gold nanomaterials and may make inroads for the excellent mid-infrared optoelectronic devices.

Two-dimensional bismuth nanosheets as prospective photo-detector with tunable optoelectronic performance.

Two dimensional Bi nanosheets have been employed to fabricate electrodes for broadband photo-detection. A series of characterization techniques including scanning electron microscopy and high-resolution transmission electron microscopy have verified that Bi nanosheets with intact lamellar structure have been obtained after facile liquid phase exfoliation. In the meanwhile, UV-vis and Raman spectra are also carried out and the inherent optical and physical properties of Bi nanosheets are confirmed. Inherited from the topological characteristics of Bi bulk counterpart, the resultant Bi nanosheet-based photo-detector exhibits preferable photo-response activity as well as environmental robustness. We then evaluate the photo-electrochemical (PEC) performance of the photodetector in 1 M NaOH and 0.5 M Na2SO4 electrolytes, and demonstrated that the as-prepared Bi nanosheets may possess a great potential as PEC-type photo-detector. Additional PEC measurements show that the current density of Bi nanosheets can reach up to 830 nA cm-2, while an enhanced responsivity (1.8 µA W-1) had been achieved. We anticipate that this contribution can provide feasibility towards the construction of high-performance elemental Bi nanosheets-based optoelectronic devices in the future.

Wavelength-locked vectorial fiber laser manipulated by Pancharatnam-Berry phase.

We report a wavelength-locked cladding-pumped ytterbium-doped fiber laser that can simultaneously emit radially and azimuthally polarized beams based on Pancharatnam-Berry phase optical elements. Multi-wavelength free running operation of the radially and azimuthally polarized laser beams can be switched to a single-wavelength one assisted by volume Bragg grating, with wavelength locked at around 1053.4 nm and spectral linewidth of 0.06 nm (FWHW). By rotating the glan-taylor polarizer, we can obtain switchable radially and azimuthally polarized beams output. The radially and azimuthally polarized beams mode purity can maintain 97.3% and 96.3% at maximum output power, and the polarization extinction ratio (PER) can reach 97.8% and 95.9% for the radially and azimuthally polarized laser, respectively.

Stable and wavelength-locked Q-switched narrow-linewidth Er:YAG laser at 1645 nm.

A stable and wavelength-locked Q-switched narrow-linewidth Er:YAG laser with compact cavity structure, utilizing a volume Bragg grating (VBG) as a wavelength selector and a pump input mirror simultaneously, is reported. It yields high energy nanosecond pulse with pulse duration of 185 ns and pulse energy of 1.36 mJ at 1 kHz pulse repetition frequency for incident pump power of 21.6 W. The central wavelength of the Er:YAG laser is locked at 1645.3 nm with a spectral 3-dB linewidth of less than 0.08 nm, which coincides to the methane (CH4) absorption-line. The output has near diffraction-limited beam quality with M2 parameter of 1.08. Our work may provide an inroad for developing more miniaturized space-based integrated path differential absorption (IDPA) lidar transmitter.

Highly efficient tunable mid-infrared optical parametric oscillator pumped by a wavelength locked, Q-switched Er:YAG laser.

A highly efficient and stable mid-infrared optical parametric oscillator is demonstrated, pumped by an electro-optic Q-switched Er:YAG laser with operating wavelength locked at 1645 nm by a volume Bragg grating. The oscillator, based on MgO-doped periodically poled lithium niobate (MgO:PPLN) crystal, yields a maximum overall average output power in excess of 1 W, corresponding to a conversion efficiency of 35.5% and a slope efficiency of 43.6%. The signal and idler wavelengths of the OPO are around ~2.7 µm and ~4.3 µm, respectively, corresponding to the two peak absorption bands of CO(2). Lasing characteristics of the oscillator, including the time evolution of the pump, signal and idler pulses at different pump power levels, are also investigated. Temperature tuning of the MgO:PPLN crystal gives signal and idler ranges of 2.67 to 2.72 µm and 4.17 to 4.31 µm, respectively.

Generation and evolution of mode-locked noise-like square-wave pulses in a large-anomalous-dispersion Er-doped ring fiber laser.

In a passively mode-locked Erbium-doped fiber laser with large anomalous-dispersion, we experimentally demonstrate the formation of noise-like square-wave pulse, which shows quite different features from conventional dissipative soliton resonance (DSR). The corresponding temporal and spectral characteristics of a variety of operation states, including Q-switched mode-locking, continuous-wave mode-locking and Raman-induced noise-like pulse near the lasing threshold, are also investigated. Stable noise-like square-wave mode-locked pulses can be obtained at a fundamental repetition frequency of 195 kHz, with pulse packet duration tunable from 15 ns to 306 ns and per-pulse energy up to 200 nJ. By reducing the linear cavity loss, stable higher-order harmonic mode-locking had also been observed, with pulse duration ranging from 37 ns at the 21st order harmonic wave to 320 ns at the fundamental order. After propagating along a piece of long telecom fiber, the generated square-wave pulses do not show any obvious change, indicating that the generated noise-like square-wave pulse can be considered as high-energy pulse packet for some promising applications. These experimental results should shed some light on the further understanding of the mechanism and characteristics of noise-like square-wave pulses.

Watt-level passively mode-locked Er(3+)-doped ZBLAN fiber laser at 2.8 µm.

We experimentally demonstrated a stable, high-average-power, continuous-wave (CW) passively mode-locked Er(3+)-doped ZBLAN fiber laser at 2.8 µm based on a semiconductor saturable absorber mirror. A stable mode-locked laser with a signal-to-noise ratio of 52 dB and a slope efficiency of 14% was obtained. The highest average output power in excess of 1 W was generated at the incident pump power of 8.2 W, with a pulse repetition rate of 22.56 MHz and pulse duration of 25 ps. To the best of our knowledge, this is the highest average output power of a CW mode-locked ZBLAN fiber laser in the mid-infrared wavelength regime up to now.

Stable high-energy Q-switched resonantly diode-pumped Er:YAG laser at 1645 nm.

We demonstrate the generation of a stable high-energy Q-switched resonantly diode-pumped Er:YAG laser at 1645 nm in passive and active operation modes. For the passively Q-switched Er:YAG laser, the bi-layer graphene saturable absorber (SA), which was transferred onto the highly reflective cavity mirror by an improved method, was applied to deliver a stable pulse train with per-pulse energy of about 0.1 mJ. While in the active operation mode, the voltage-ON-type rubidium titanyl phosphate (RTP) Pockels cell as an electro-optic (EO) Q-switcher allows for the generation of a stable Q-switched pulse with per-pulse energy of up to 7.5 mJ. Our work may provide a basis for the development of a high-energy Er:YAG laser at 1645 nm to fulfill specific applications.

Large-energy, narrow-bandwidth laser pulse at 1645 nm in a diode-pumped Er:YAG solid-state laser passively Q-switched by a monolayer graphene saturable absorber.

Nonlinear transmission parameters of monolayer graphene at 1645 nm were obtained. Based on the monolayer graphene saturable absorber, a 1532 nm LD pumped 1645 nm passively Q-switched Er:YAG laser was demonstrated. Under the pump power of 20.8 W, a 1645 nm Q-switched pulse with FWHM of 0.13 nm (without the use of etalon) and energy of 13.5 µJ per pulse can be obtained. To the best of our knowledge, this is the highest pulse energy for graphene-based passively Q-switched Er:YAG laseroperating at 1645 nm, suggesting the potentials of graphene materials for high-energy solid-state laser applications.

A Strategy for Multigas Identification Using Multielectrical Parameters Extracted from a Single Carbon-Based Field-Effect Transistor Sensor.

Given the widespread utilization of gas sensors across various industries, the detection of diverse and complex target gases presents a significant challenge in designing sensors with multigas detection capability. Although constructing a sensor array with widely used chemiresistive gas sensors is one solution, it is difficult for a single chemiresistive gas sensor to simultaneously detect different gases, as it can only detect a single target gas. The intrinsic reason for this bottleneck is that chemiresistive gas sensors rely entirely on the resistivity as the unique parameter to evaluate the diverse gas sensing properties of sensors, such as sensitivity, selectivity, etc. Herein, a field-effect transistor (FET) with abundant electrical parameters is employed to prepare a gas sensor for the detection of a variety of gases. Semiconducting carbon nanotubes (CNTs) are selected as the channel material, which is modified by Pd nanoparticles to enhance the gas sensing properties of the sensors. By extracting various electrical parameters such as transconductance, threshold voltage, etc. from the transfer characteristic curves of FET, a correlation between multielectrical parameters and various gas detection information is established for subsequent data analysis. Through the utilization of the principal component analysis algorithm, the identification of six gases can be finally achieved by relying solely on a single carbon-based FET-type gas sensor. We hope our work can solve the bottleneck of multigas identification by a single sensor in principle and is expected to reduce the system complexity and cost caused by the design of sensor arrays, offering a valuable guidance for multigas identification technology.

Soliton trapping of dispersive waves in photonic crystal fiber with two zero dispersive wavelengths.

Based on the generalized nonlinear Schrödinger equation, we present a numerical study of trapping of dispersive waves by solitons during supercontinuum generation in photonic crystal fibers pumped with femtosecond pulses in the anomalous dispersion region. Numerical simulation results show that the generated supercontinuum is bounded by two branches of dispersive waves, namely blue-shifted dispersive waves (B-DWs) and red-shifted dispersive waves (R-DWs). We find a novel phenomenon that not only B-DWs but also R-DWs can be trapped by solitons across the zero-dispersion wavelength when the group-velocity matching between the soliton and the dispersive wave is satisfied, which may led to the generation of new spectral components via mixing of solitons and dispersive waves. Mixing of solitons with dispersive waves has been shown to play an important role in shaping not only the edge of the supercontinuum, but also its central part around the higher zero-dispersion wavelength. Further, we show that the phenomenon of soliton trapping of dispersive waves in photonic crystal fibers with two zero-dispersion wavelengths has a very close relationship with pumping power and the interval between two zero-dispersion wavelengths. In order to clearly display the evolution of soliton trapping of dispersive waves, the spectrogram of output pulses is observed using cross-correlation frequency-resolved optical gating technique (XFROG).

Machine Learning-Assisted Large-Area Preparation of MoS2 Materials.

Molybdenum disulfide (MoS2) is a layered transition metal-sulfur compound semiconductor that shows promising prospects for applications in optoelectronics and integrated circuits because of its low preparation cost, good stability and excellent physicochemical, biological and mechanical properties. MoS2 with high quality, large size and outstanding performance can be prepared via chemical vapor deposition (CVD). However, its preparation process is complex, and the area of MoS2 obtained is difficult to control. Machine learning (ML), as a powerful tool, has been widely applied in materials science. Based on this, in this paper, a ML Gaussian regression model was constructed to explore the growth mechanism of MoS2 material prepared with the CVD method. The parameters of the regression model were evaluated by combining the four indicators of goodness of fit (r2), mean squared error (MSE), Pearson correlation coefficient (p) and p-value (p_val) of Pearson's correlation coefficient. After comprehensive comparison, it was found that the performance of the model was optimal when the number of iterations was 15. Additionally, feature importance analysis was conducted on the growth parameters using the established model. The results showed that the carrier gas flow rate (Fr), molybdenum sulfur ratio (R) and reaction temperature (T) had a crucial impact on the CVD growth of MoS2 materials. The optimal model was used to predict the size of molybdenum disulfide synthesis under 185,900 experimental conditions in the simulation dataset so as to select the optimal range for the synthesis of large-size molybdenum disulfide. Furthermore, the model prediction results were verified through literature and experimental results. It was found that the relative error between the prediction results and the literature and experimental results was small. These findings provide an effective solution to the preparation of MoS2 materials with a reduction in the time and cost of trial and error.

Research Progress of Photo-/Electro-Driven Thermochromic Smart Windows.

Thermochromic smart windows can automatically control solar radiation according to the ambient temperature. Compared with photochromic and electrochromic smart windows, they have a stronger applicability and lower energy consumption, and have a wide range of application prospects in the field of building energy efficiency. At present, aiming at the challenge of the high transition temperature of thermochromic smart windows, a large amount of innovative research has been carried out via the principle that thermochromic materials can be driven to change their optical performance by photothermal or electrothermal effects at room temperature. Based on this, the research progress of photo- and electro-driven thermochromic smart windows is summarized from VO2-based composites, hydrogels and liquid crystals, and it is pointed out that there are two main development trends of photo-/electro-driven thermochromic smart windows. One is exploring the diversified combination methods of photothermal materials and thermochromic materials, and the other is developing low-cost large-area heating electrodes.

Bismuth Telluride nanocrystal: broadband nonlinear response and its application in ultrafast photonics.

We come up with a hybrid liquid exfoliation method to prepare bismuth telluride nanocrystals efficiently and cost-effectively. The nonlinear transmittance of the nanocrystals has been characterized with Z-scan technique, which can manifest its broadband saturable absorption behavior experimentally. The as-fabricated nanocrystals were integrated onto fiber end facet to form a fiber compatible nonlinear absorption device with optical deposition method, which was then used to modulate the fiber laser with different cavity configurations to deliver pulsed laser successfully. The noise-like pulse and dissipative soliton have been obtained with wavelength centered at 1562 nm and 1068 nm, respectively. These results confirm the effectiveness of the hybrid liquid exfoliation method to prepare bismuth telluride into nanocrystals, and the broadband nonlinear optical response and ultrafast photonics application potential of the nanocrystals.

Graphene Oxide: A Perfect Material for Spatial Light Modulation Based on Plasma Channels.

The graphene oxide (GO) is successfully prepared from a purified natural graphite through a pressurized oxidation method. We experimentally demonstrate that GO as an optical media can be used for spatial light modulation based on plasma channels induced by femtosecond pulses. The modulated beam exhibits good propagation properties in free space. It is easy to realize the spatial modulation on the probe beam at a high concentration of GO dispersion solutions, high power and smaller pulse width of the pump beam. We also find that the spatial modulation on the probe beam can be conveniently adjusted through the power and pulse width of pump lasers, dispersion solution concentration.

Expression of CD39 mRNA is altered in the peripheral blood of patients with allergic asthma.

The ectoenzyme CD39 hydrolyzes extracellular adenosine 5'-triphosphate (ATP), which possesses pro-inflammatory properties. However, the role of CD39 in allergic asthma has not been fully elucidated. A total of 18 patients with persistent asthma who were allergic to house dust mites and 19 healthy volunteers were enrolled in this study. The expression of CD39, GATA3, RAR-related orphan receptor γ (ROR-γt) and forkhead box P3 (FoxP3) mRNA in peripheral blood mononuclear cells (PBMCs) was determined by SYBR-Green I quantitative polymerase chain reaction (qPCR). The cytokines interleukin (IL)-4, IL-17A, transforming growth factor ß (TGF-ß) and DP.sIgE were detected by enzyme-linked immunosorbent assay. Our data demonstrated that the expression of CD39 mRNA in PBMCs from asthmatic patients was significantly lower compared to that in normal controls [(1.49±0.59)×10-3 vs. (2.17±0.77)×10-3, respectively; P<0.01]. CD39 mRNA was negatively correlated with serum IL-4, IL-17A and GATA3 expression (r=-0.468, P<0.05; r=-0.550, P<0.05; and r=-0.424, P<0.01, respectively) and positively correlated with FoxP3 and TGF-ß expression (r=0.373, P<0.05; and r=0.425, P<0.05, respectively). There was no obvious correlation between CD39 and ROR-γt expression (r=-0.259, P=0.122). These data suggested that CD39 mRNA expression was downregulated in allergic asthma, which was positively correlated with serum IL-4, IL-17A and GATA3 expression and negatively correlated with serum TGF-ß and FoxP3 expression, whereas there was no correlation with ROR-γt. Therefore, it was hypothesized that CD39 may participate in the occurrence and progression of allergic asthma.