RESUMEN
Semiconductor materials with wide bandgaps are extensively employed for gas detection due to their advantages of low cost, high sensitivity, fast speed, excellent stability, and distinctive selectivity. Previous studies have reported on different kinds of semiconductor materials and their complex synthesis procedures. However, the research progress on gas-sensitive mechanisms seriously lags behind the performance improvement. The research route of the gas-sensing mechanism is not clear, resulting in an unclear development direction of novel sensitive materials. This review aims to summarize existing approaches and their progress on the interpretation of gas-sensing mechanisms in semiconductors, such as the calculations based on density functional theory, semiconductor physics, and in situ experiments. Ultimately, a reasonable route for the mechanism investigation has been proposed. It guides the development direction of novel materials and reduces the cost of screening highly selective materials. Overall, this review can provide helpful guidance concerning the gas-sensitive mechanism for scholars.
RESUMEN
An air-insulated power equipment adopts air as the insulating medium and is widely implemented in power systems. When discharge faults occur, the air produces decomposition products represented by NO2. The efficient NO2 sensor enables the identification of electrical equipment faults. However, single-sensor-dependent NO2 detection is vulnerable to interfering gases. Implementing the sensor array could reduce the interference and improve detection efficiency. In the field of NO2 detection, In2O3 sensors have exhibited tremendous advantages. In our work, four composites based on In2O3 are integrated into sensor arrays, which could detect 250 ppb of NO2 and exhibit excellent selectivity when simultaneously exposed to CO. To further reduce the impact of humidity on gas-sensing performance, a convolutional neural network and a long short-term memory model equipped with an attention mechanism are proposed to evaluate NO2 concentration within 1 ppm, and the detection error is 63.69 ppb. In addition, the NO2 concentration estimation platform based on a microgas sensor is established to detect air discharge faults. The average concentration of NO2 generated by 10 consecutive discharge faults at 15 kV is 726.58 ppb, which indicates severe discharge in the switchgear. Our NO2 estimation method has great potential for large-scale deployment in low- and medium-voltage switchgears.
RESUMEN
A difficult issue restricting the development of gas sensors is multicomponent recognition. Herein, a gas-sensing (GS) microchip loaded with three gas-sensitive materials was fabricated via a micromachining technique. Then, a portable gas detection system was built to collect the signals of the chip under various decomposition products of sulfur hexafluoride (SF6). Through a stacked denoising autoencoder (SDAE), a total of five high-level features could be extracted from the original signals. Combined with machine learning algorithms, the accurate classification of 47 simulants was realized, and 5-fold cross-validation proved the reliability. To investigate the generalization ability, 30 sets of examinations for testing unknown gases were performed. The results indicated that SDAE-based models exhibit better generalization performance than PCA-based models, regardless of the magnitude of noise. In addition, hypothesis testing was introduced to check the significant differences of various models, and the bagging-based back propagation neural network with SDAE exhibits superior performance at 95% confidence.