RESUMEN
Luminescent copper nanoclusters (Cu NCs) are chosen to functionalize Ti3C2Tx MXene flakes to form a new kind of nanohybrid. It was applied to the determination of glutathione (GSH) via photoluminescence (PL). The Cu NCs and MXene flakes are in close contact, and the blue PL of the Cu NCs (with excitation/emission peaks at 380/425 nm) is quenched. The addition of GSH triggers the separation of the nanohybrid. This results in the recovery of PL. GSH also promotes the PL of Cu NCs via host-guest interactions. Thus, target recognition, corresponding signal output and further magnification are accomplished in a single step. Under optimum conditions, the nanohybrid can detect GSH in the 5.0 to 100 µM concentration range and with a 3.0 µM detection limit. The assay is very specific and shows high selectivity towards metal ions, small biomolecules, amino acids, and thiol containing molecules. Graphical abstractLuminescent copper nanoclusters are used to functionalize Ti3C2Tx MXene flakes, forming a nanohybrid, which is applied to detect glutathione. Target recognition, signal output and magnification are accomplished in a single step, resulting in high selectivity.
RESUMEN
Many hybrid electrodes for supercapacitors (SCs) are a reckless combination without proper structural design that keeps them from fulfilling their potential. Herein, we design a reduced graphene oxide/poly(3,4-ethylenedioxythiophene)/polyaniline (RGO/PEDOT/PANI) hybrid with hierarchical and porous structure for high-performance SCs, where components fully harness their advantages, forming an interconnected and conductive framework with substantial reactive sites.Thus, this hybrid achieves a high capacitance of 535 F g-1 along with good rate capability and cyclability. The planar SC based on this hybrid deliver an energy density of 26.89 Wh kg-1 at a power density of 800 W kg-1. The linear SC developed via modifying a cotton yarn with the hybrid exhibits good flexibility and structural stability, which operates normally after arbitrary deformations. This work provides a beneficial reference for developing SCs.
RESUMEN
Owing to its electronic conductivity and electrochemical reactivity, polyaniline (PANI) can serve as the cathode for rechargeable zinc-ion batteries (ZIBs). However, it suffers from fast deactivation and thus performance deterioration because of spontaneous deprotonation during charge/discharge. Here, we report an effective strategy to improve the electrochemical reactivity and stability of the PANI-based cathode by constructing a π-electron conjugated system between PANI and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) on carbon nanotubes (CNTs). The impressive performance of the post-treated CNTs-PANI-PEDOT:PSS (t-CNTs-PA-PE) cathode is largely attributed to the -SO3-H+ groups in PSS, which acts as an internal proton reservoir and provides enough H+ for PANI's protonation, thus promoting its electrochemical activity and reversibility. Besides, the strong interactions between PANI and PEDOT:PSS assist the stretching of π-π conjugation chains, bringing about enhanced electronic conductivity. Consequently, the t-CNTs-PA-PE cathode achieves a high capacity of 238 mA h g-1, together with good rate capability and long-term stability (over 1500 cycles with 100% Coulombic efficiency). Through exerting the freestanding t-CNTs-PA-PE, a flexible ZIB was further constructed with both outstanding electrochemical properties and superior high safety. This work demonstrates the availability of conducting polymer cathodes for high-performance ZIBs, fulfilling the need of flexible electronics.
RESUMEN
Ti3C2T x (MXene) exhibits attractive properties in different applications. However, traditional synthesis leads to unsatisfactory yield of two-dimensional (2D) Ti3C2T x, e.g., lower than 20%, which stems from the strong interactions of potential Ti-Ti bonds and residual Ti-Al bonds between the adjacent Ti3C2 layers, hindering the effective intercalation and delamination. Herein, we propose a facile hydrothermal-assisted intercalation (HAI) strategy to boost the yield of 2D sheets, achieving a record high value of 74%. This HAI assists the diffusion and intercalation of reagent effectively, promoting the subsequent delamination; meanwhile, an antioxidant is applied to protect these Ti3C2T x from oxidation during the HAI process. Therefore, massive Ti3C2T x 2D sheets can be easily synthesized. Thanks to the synergistic effect of high conductivity and substantial terminated functionalities, these Ti3C2T x 2D sheets show promising application in supercapacitor, providing a high capacitance of 482 F g-1. Besides, the ultrafast carrier dynamics results of Ti3C2T x 2D sheets clearly imply the promising application in photocatalysis due to the relatively long bleaching relaxation time. Our work not only paves the way for the mass production of Ti3C2T x 2D sheets but also provides insights into their electronic and optical properties.