RESUMEN
Soil heavy metal (Cr, Cu, Zn, Pb, Cd, V, As) concentrations in different areas were analyzed to investigate the effects of different industrial activities on heavy metal pollution status, potential ecological risk, and human health risk in Panzhihua. Our results showed that Cu and V enrichment in soil was due to ore smelting. Soil Cr accumulation was related to coal ore mining. Soil Cd, Zn, As, and Pb enrichment was attributed to high-temperature coal combustion. Under the effect of industrial activities, soils were moderately contaminated with Cd, uncontaminated to moderately contaminated with As and Zn, and uncontaminated with Cr, Cu, V, and Pb. Soil heavy metal potential ecological risk was considerable, and non-carcinogenic risks and carcinogenic risks of soil heavy metals were acceptable for adults but unacceptable for children. Thermal power generation was the dominated industrial activity that influence the soil heavy metal concentrations and environmental risks in Panzhihua, which posed considerable potential ecological risks and unacceptable heavy metal non-carcinogenic risks and As carcinogenic risk to both adults and children. This study indicates that industrial activities have great effects on heavy metal pollution, ecological risks, and health risk, and more attention should be paid to the ecological risk and health risks brought by thermal power generation.
Asunto(s)
Metales Pesados , Contaminantes del Suelo , Adulto , Niño , China , Monitoreo del Ambiente , Humanos , Metales Pesados/análisis , Metales Pesados/toxicidad , Medición de Riesgo , Suelo , Contaminantes del Suelo/análisisRESUMEN
Urban activity emissions have important ecological significance to bacterial communities' spatial and temporal distribution and the mechanism of bacterial community construction. The mechanism of bacterial community construction is the key to community structure and lifestyle, and the influence of this aspect has not been thoroughly studied. This study analyzed the response of bacteria in water and sediment in different seasons to urban activities in Jinsha River. The results showed that the influence of urban activities on bacterial community structure in sediment was greater than that in water. The input of pollution in different regions changed the diversity and abundance of water and sediments bacteria and promoted bacterial community reconstruction to a certain extent. Co-network analysis found that many metal-mediated species are core species within the same module and can be used to mitigate pollution caused by metal or organic pollutants due to interspecific solid interactions. Different potential pollution sources around urban rivers affect the metabolic function of bacteria in aquatic ecosystems and promote the detoxification function of bacteria in different media. The results of this study supplement our understanding of the characteristics of microbial communities in urban river systems and provide clues for understanding the maintenance mechanism of microbial diversity in multi-pollution environments.
RESUMEN
Phosphate is present in all kinds of industrial wastewater; how to remove it to meet the strict total phosphorus discharge standards is a challenge. This study used a one-step foaming technique to fill polyurethane foam (PUF) with ZnO, taking advantage of PUF's excellent features like its porous network, lightweight, hydrophilicity, and abundance of binding sites to create ZnO/PUF composites with high adsorption capacity and exceptional separation properties. The adsorption isotherms, kinetics, starting pH, and matrix impacts of ZnO/PUF composites on phosphate were examined in batch studies. The results showed that the composites had good adsorption performance for phosphate with a saturated adsorption capacity of 460.25 mg/g. The quasi-secondary kinetic and Langmuir models could better describe the adsorption process, which belonged to the chemical adsorption of monomolecular layers. The composites' ability to treat phosphates in complicated waters was shown by their ability to retain a high adsorption capacity in the pH range of 3-6. In column experiments, the composite also maintains a good affinity for phosphate during dynamic adsorption. Multiple characterizations indicate that the adsorption mechanism is a combined effect of ligand exchange and electrostatic interactions. Therefore, this study provides valuable insights for practical phosphorus-containing wastewater treatment.
Asunto(s)
Fosfatos , Poliuretanos , Óxido de Zinc , Adsorción , Fosfatos/química , Óxido de Zinc/química , Poliuretanos/química , Contaminantes Químicos del Agua/química , Aguas Residuales/química , Cinética , Concentración de Iones de Hidrógeno , Purificación del Agua/métodosRESUMEN
Plant uptake can reduce soil cadmium (Cd) pollution, while how to exactly predict plant Cd uptake in industrial or mining areas during vegetation restoration remains unexplored. Taking Heteropogon contortus as the object plant, we predicted plant Cd uptake in the Majiatian tailings reservoir during 48-year vegetation restoration by the methods of soil total Cd, DGT (diffusive gradients in thin films technique) and acetic acid (HAc) extraction. Meanwhile, we explored the effects of soil properties on the accuracy of the prediction. Total Cd concentrations in the soils exhibited a better prediction of plant Cd uptake relative to the methods of HAc extraction and DGT. However, the DGT method effectively predicted plant Cd uptake at low Cd supply (lower than 0.42 µg/L), probably because of the dominant diffusion limitation by plants. The prediction of plant Cd uptake by HAc extraction was improved when combined with soil pH. Our results indicate that with increasing external Cd inputs during the vegetation restoration, soil total Cd and traditional extraction method in combination with soil properties are effective ways to predict plant Cd uptake, especially when the Cd fractions cannot be measured by DGT. However, the DGT method works once plant Cd uptake dominated by diffusion limitation despite the interference in soil properties.
Asunto(s)
Cadmio , Contaminantes del Suelo , Disponibilidad Biológica , Cadmio/análisis , Minería , Suelo/química , Contaminantes del Suelo/análisisRESUMEN
The purpose of this study was to assess the association of blood pressure (BP) measurements with the risk of cardiovascular disease (CVD) and examine whether central systolic BP (CSBP) predicts CVD better than brachial BP measurements (SBP and pulse pressure [PP]). Based on a cross-sectional study conducted in 2009-2010 with follow-up in 2016-2017 among 35- to 64-year-old subjects in China, we evaluated the performance of non-invasively predicted CSBP over brachial BP measurements on the first CVD events. Each BP measurement, individually and jointly with another BP measurement, was entered into the multivariate Cox proportional-hazards models, to examine the predictability of central and brachial BP measurements. Mean age of participants (n = 8710) was 50.1 years at baseline. After a median follow-up of 6.36 years, 187 CVD events occurred. CSBP was a stronger predictor for CVD than brachial BP measurements (CSBP, 1-standard deviation increment HR = 1.49, 95%CI: 1.31-1.70). With CSBP and SBP entering into models jointly, the HR for CSBP and SBP was 1.28 (1.04-1.58) and 1.22 (0.98-1.50), respectively. With CSBP and PP entering into models jointly, the HR for CSBP and PP was 1.51 (1.28-1.78) and 0.98 (0.83-1.15), respectively. For subgroup analysis, the association of CSBP with CVD was stronger than brachial BP measurements in women, those with hypertension and obesity. In the middle-aged Chinese population, noninvasively estimated CSBP may offer advantages over brachial BP measurements to predict CVD events, especially for participants with higher risk. These findings suggest prospective assessment of CSBP as a prevention and treatment target in further trials.