Investigating phosphorus limitation in a fixed bed filter with phosphorus and nitrogen profile measurements.

In 2000, the European Union adopted the European Water Framework Directive (WFD) (European Commission, 2000). The WFD focuses on increasingly stringent nutrient standards including ultra low nitrogen (< 2.2 mg N-total/L) and phosphorus concentrations (< 0.15 mg total phosphorus/L) in receiving surface waters and in relevant point sources like wastewater treatment plant (WWTP) effluent. Expansion of WWTPs with advanced post-treatment processes, like effluent filtration, is widely proposed to meet possible future effluent discharge standards. When combining biological nitrate-nitrogen and chemical phosphorus removal in one filter, phosphorus limitation in the denitrifying process may occur. This study investigated where in the filter bed and under which conditions phosphorus limitation occurs. Profile measurements for nitrate, nitrite, and orthophosphorus (PO4-P) combined with chemical oxygen demand (COD) and 02 were conducted. Results showed that the required PO4-P/NOx-N ratio is approximately 0.006 mg/mg after phosphorous precipitation and flocculation. Profile measurements have proven to be an applicable and useful tool. It showed how nitrate and orthophosphorus are removed through the filter bed based on the PO4-P/NOx-N ratio. When orthophosphorus is removed more rapidly and efficiently compared to nitrate, the PO4-P/NOx-N ratio decreases. When PO4-P/NOx-N ratio thresholds are approximately 0.006 mg/mg for a certain period of time and water temperatures varied significantly, orthophosphorus limitation may occur. Changing the filter-bed configuration or decreasing the coagulant dosage can prevent limitation of the denitrifying process because of a phosphorous shortage.

Particle counting as a tool to predict filterability in membrane bioreactors activated sludge?

Activated sludge quality is one of the major factors influencing flux decline in membrane bioreactors (MBRS). Sludge filterability is a recognized parameter to characterize the physical properties of activated sludge. Decrease in filterability is linked to a higher number of submicron particles. In our present research we studied whether particle counting techniques can be used to indicate deflocculation of the sludge suspended fraction to submicron particles, causing the aforementioned filterability decrease. A total number of 105 activated sludge samples were collected in four full scale municipal MBRS. Samples were tested for filterability and particle counting in the range 2-100 microm. In 88% of the membrane tank samples the filterability varied between good and poor, characterized by the deltaR20, being 0 < deltaR20 < 1. Filterability varied following the season of the year, stability of the MBR operation and recirculation ratio. The membrane tank filterability can be improved by applying low recirculation ratio between MBR tanks. The applied particle counting methodology generated reproducible and reliable results in the range 10-100 microm. Results show that differences in filterability cannot be explained by variations in particle size distribution in the range 10-100 microm. However, measurable deflocculation might be masked by the large numbers of particles present. Therefore, we cannot exclude the suspended particles as a possible source of submicron particles that are subsequently responsible for MBR sludge filterability deterioration.

Experiences on dual media filtration of WWTP effluent.

This research is legislation driven by the European Water Framework Directive (WFD) and the Dutch Fourth Memorandum on Water Management. The objective of this research is to achieve the removal of total nitrogen and total phosphorus by Dual Media Filtration. The target value during this research for total nitrogen is 2.2 mg/L and for total phosphorus 0.15 mg/L. The results show that for NOx-N concentrations in the WWTP effluent up to 10 mg/L, a stable operation of the process can be reached with removal rates of 80% to 90%. The maximum nitrogen removal rate was 3.5 kg N/(m3.d). Above 10 mg/L a risk of filter bed clogging occurred. When the orthophosphorus concentration in the WWTP effluent exceeds the maximum of 0.3 mg/L, the total phosphorus concentration in the filtrate water will exceed the target value of 0.15 mg P-total/L. Temperature has a large impact in the phosphorus removal; the optimum temperature range is within 13 degrees C-18 degrees C. In conclusion, Dual Media Filtration is capable of producing reusable water with total phosphorus concentrations of <0.15 mg/L, under the condition that the wastewater treatment plant produces WWTP effluent with steady concentrations for orthophosphorus (<0.3 mg PO4-P/L). To reach total nitrogen concentrations in the filtrate water of <2.2 mg/L a NOx-N removal efficiency of nearly 100% is required.

Minimising the risk on phosphorus limitation; an optimised coagulant dosage system.

In the near future the WWTP Horstermeer will be confronted with more stringent requirements. Important factor in this respect is the European Water Framework Directive 2000/60/EC. Within the WFD approach the focus is more and more on low nitrogen (<2.2 mg N-total/L) and phosphorus concentrations (<0.15 mg P-total/L) in WWTP effluent. Therefore, research has been initiated at the Horstermeer WWTP to investigate the possibilities of simultaneous nutrient removal with filtration techniques. After nitrite accumulation, caused by phosphorus limitation, was measured in the filtrate water of the 1-STEP filter, research has started. The objective of this research is to minimise the risk on the inhibition of denitrification by phosphorus limitation and to decrease the dosage of coagulant. Therefore a new coagulant dosage system is developed. The back-ground of the coagulant dosage system, the results and cost savings are discussed in this article. When the PO4-P/NOx-N ratio in the WWTP effluent becomes below 0.06 mg/mg phosphorus limitation may occur. The results for phosphorus and nitrogen removal are equal or improved compared to the yearly average of 2008. The results show a more stable removal process and a reduction of the coagulant dosage for the coagulant dosage system of 11% when compared to a continuous dosage ratio of MeP 4 mol/mol.

Advanced treatment of WWTP effluent with filtration leading to a pretreatment technique for membrane filtration.

In 2000 the European Union introduced the Water Framework Directive (WFD). The aim of the WFD is having an ecological and chemical balance for all surface waters in Europe in 2015. The European Commission identified 33 priority substances and their maximum allowable concentrations, FHI-values (Fraunhofer Institute), which are specified in the Annex of the WFD. The objective of this research is to achieve the removal of suspended solids, nitrogen and total phosphorus together with priority substances. All these substances will be removed in one filter called a "One Step Total Effluent Polishing filter" i.e. 1-STEP(®) filter. For this purpose a filter pilot plant was tested at the WWTP Horstermeer. The results show that the filter can fulfil the target values in the filtrate water for total nitrogen (2.2 mg Ntotal/L) and total phosphorus (0.15 mg Ptotal/L). The majority of the priority (hazardous) substances in the WWTP effluent are already below the detection limit. Due to the low concentration ranges, the results on the removal of medicine and pesticides are only indicative. A decreasing tendency in the removal efficiency is shown for all measured compounds. The average specific ultrafiltration resistance (SUR) value decrease of the filter is 55% and the final value is always below 5·10(12) m(-2). This indicates that the filtrate water of the filter is very well filterable and can be used as ultrafiltration feedwater.

Phosphorus and nitrogen profile measurements to locate phosphorus limitation in a fixed bed filter.

The European Union presented in 2000 the European Water Framework Directive (WFD). Within the WFD approach the focus is more and more on ultra low nitrogen (<2.2 mg N-total/L) and phosphorus concentrations (<0.15 mg P-total/L) in waste water treatment plant (WWTP) effluent. Nitrogen concentrations of 2.2 mg N-total/L can be reached with denitrifying filters as a tertiary treatment step. When combining nitrogen and chemical phosphorus removal in a filter, phosphorus limitation may occur. After nitrite accumulation, caused by phosphorus limitation, was measured in the filtrate water of the dual media filter, research was started to locate, to understand and to solve the problem. Profile measurements for nitrate, nitrite and orthophosphorus (PO(4)-P) combined with COD and O(2) were conducted. Results show that the minimal required PO(4)-P/NO(x)-N ratio is 0.006 mg/mg after coagulation and flocculation. Profile measurements have proven to be a useful tool. It showed how nitrate and orthophosphorus are removed through the filter bed and it showed the consequences for the PO(4)-P/NO(x)-N ratio. When orthophosphorus is removed more rapidly compared to nitrate the PO(4)-P/NO(x)-N ratio decreases. When the PO(4)-P/NO(x)-N ratio becomes below 0.006 mg/mg for a certain period of time, orthophosphorus limitation occurs. The solution can be either changing the filter bed configuration or decreasing the coagulant dosage.

Innovative phosphorus distribution method to achieve advanced chemical phosphorus removal.

Since November 2006 a large-scale research project has been carried out at Wastewater Treatment Plant (WWTP) Leiden Zuidwest (within the Rijnland District Water Control Board). This research focuses on advanced removal of nutrients (phosphorus and nitrogen), heavy metals and priority hazardous substances from WWTP-effluent with different treatment techniques to reach an effluent quality, which could be required in the future by the Water Framework Directive (WFD) 2000/60/EC. Within the WFD-approach to guarantee an ecological and a chemical "good status" of the receiving water bodies, the focus is more and more on ultra low phosphorus concentrations in effluent. To be able to reach these stringent goals more insight into phosphorus components in effluent is required. A new method of distribution of phosphorus is used to determine orthophosphate, metal bound phosphorus, dissolved "organic" phosphorus and particulate "organic" phosphorus. This knowledge about the distribution of phosphorus makes it possible to compare different filter concepts and different process parameters, for example flocculation time, initial mixing energy and filtration rates. When comparing (filter concept 1) continuous sand filtration with (filter concept 2) dual media filtration for phosphorus removal, it appears that, a higher percentage of the formed metal bound phosphorus will pass the continuous sand filter. The ortho-phosphorus which is not bound to trivalent metal after coagulation will remain dissolved ortho-phosphorus and will pass the filter bed. This is shown in both filter concepts. The dissolved 'organic' phosphorus decreases after flocculation and the particulate 'organic' phosphorus increases which suggests that it may be colloidal or associated with colloidal material. With continuous sand filtration 50% of the particulate phosphorus is removed. In the dual media filter even 86% of the particulate phosphorus is removed.

Removal of nitrogen, phosphorus and other priority (hazardous) substances from WWTP effluent.

More stringent effluent criteria will be required in the near future for the so-called priority substances listed in the Annex of the European Water Framework Directive (WFD) 2000/60/EC. This includes heavy metals, volatile and semi-volatile organic substances, pesticides and polychlorinated biphenyls. The Fraunhofer Institute suggested FHI values for these substances in water. National Dutch legislation, the Vierde Nota WaterHuishouding (NWH) introduced in 1998 'maximum tolerable risk concentrations' (MTR). These include requirements for nutrients: P(tot) < 0.15 mg/l and N(tot) < 2.2 mg/l. The MTR values are being used until the FHI values become effective. Investigation into possible effluent polishing techniques is required in order to reach these objectives. During pilot research with tertiary denitrifying multi-media and biological activated carbon filtration at the WWTP Utrecht in The Netherlands, simultaneous nutrient removal to MTR quality was observed. Furthermore, simultaneous removal of heavy metals, 17beta-estradiol, bisphenol A and nonylphenols to extreme low concentrations by denitrifying activated carbon filtrated is achieved.

Behaviour of heavy metals during tertiary bio-filtration.

More stringent water quality parameters in the Annex of the Water Framework Directive 2000/60/EC led to the introduction of "Maximum Tolerable Risk concentrations" (MTR-values) in the national legislation in The Netherlands (Vierde Nota Waterhuishouding). The MTR-values give limitations for the concentrations of e.g. heavy metals (HM's) but also for nutrients: Ntot < 2.2 mg/l, Ptot <0.15 mg/l. Investigations of HM removal during denitrifying flocculation filtration are conducted on the effluent of a typical modern Dutch WWTP. Because of low concentrations of HM's in the feed water, a cocktail of copper, nickel and zinc chloride (approximately equal 150-200 microg/l) is dosed before filtration. Preliminary jar tests and filtration tests with media filtration in pilot-scale and lab-scale are conducted. The results show high removal of nickel and zinc during jar tests with dosing of powdered activated carbon. During filtration tests at pilot-scale the bounded fraction of copper and zinc is highly removed. All three HM's are removed in the lab-scale activated carbon filter. After dosing, nickel is found mainly in the dissolved form, but it is removed in the lab-scale activated carbon filter. The removal of HM's via adsorption subsequently leads to a discussion on the toxicity of HM's and their bio-availability.

Temperature and conductivity as control parameters for pollution-based real-time control.

Most sewer system performance indicators are not easily measurable online at high frequencies in wastewater systems, which hampers real-time control with those parameters. Instead of using a constituent of wastewater, an alternative could be to use characteristics of wastewater that are relatively easily measurable in sewer systems and could serve as indicator parameters for the dilution process of wastewater. This paper focuses on the possibility to use the parameters of temperature and conductivity. It shows a good relation of temperature and conductivity with the dilution of DWF (dry weather flow) during WWF (wet weather flow) a monitoring station in Graz, Austria, as an example. The simultaneous monitoring of both parameters leads to valuable back-up information in case one parameter (temperature) shows no reaction to a storm event. However, for various reasons, anomalies occur in the typical behaviour of both parameters. The frequency and extent of these anomalies will determine the usefulness of the proposed parameters in a system for pollution-based real-time control. Both the normal behaviour and the anomalies will be studied further by means of trend and correlation analyses of data to be obtained from a monitoring network for the parameters of interest that is currently being set up in the Netherlands.

Occurrence of EPS in activated sludge from a membrane bioreactor treating municipal wastewater.

EPS are supposed to be among the causes of membrane fouling in membrane bioreactors (MBR). In this work they are measured as total proteins and total polysaccharides. Theoretical and empirical considerations of biomass membrane filtration lead to the conclusion that EPS in the water phase is decisive for the filterability of activated sludge. In this study therefore different ways of separating the water phase from the biomass are investigated, where a simple filtration over a paper filter turned out to be sufficient. Subsequently, a simple batch test set up was used to investigate the influence of substrate conditions on the amount of EPS in the water phase. Dilution of the biomass does not result in changes. Dilution together with substrate addition leads to an increase both in proteins and polysaccharides. Replacement of the water phase leads to no significant changes in protein concentration, but polysaccharide concentration may vary considerably. This phenomenon is more pronounced after replacement of the water phase and substrate addition.

Interactions within the wastewater system: requirements for sewer processes modelling.

Today's focus on wastewater system optimisation necessitates the development of knowledge on the interactions between sewer systems and wastewater treatment, since these interactions have often been neglected in the past. In this paper the question is discussed to what extent it is favourable and possible to include dynamic changes of wastewater quality in wastewater system optimisation studies. The sensitivity of the wastewater treatment works to influent fluctuations proved to be the key issue in determining which sewer processes are involved in the dynamic interactions between sewer systems and treatment works. The preliminary results show the importance of a good description of the transport processes involving the double and suspended fractions.

The role of microparticles in dead-end ultrafiltration of wwtp-effluent.

Ultrafiltration is considered as an interesting polishing technique for effluent of wastewater treatment plants (wwtp-effluent). Results in pilot-scale experiments indicated that microparticles might dominate the filtration characteristics. In this article the results of investigations on the role of microparticles on the filterability of effluent is described. Calculation effects on particle size distributions of effluent showed that particles smaller than 2.0 microm predominantly influence the filterability of the wwtp-effluent. Additionally, experiments were performed on the filterability of size fractions of effluent. Effluent was fractionated with laboratory filters (pore diameter 5.0, 1.2, 0.45, 0.2 and 0.1 microm). The filterability of this pre-filtered effluent in applying ultrafiltration was evaluated by measurement of the SUR, a new parameter for measurement of the filterability of effluent. The results showed that filterability of the effluent was mainly influenced by 40% to 57% by the fraction larger than 0.1 microm and smaller than 0.2 microm, which is five to twenty times larger than the ultrafiltration membrane pores. Pre-treatment of the effluent by coagulation or sand filtration showed only minor influence on these results.

Influence of the size of membrane foulants on the filterability of WWTP-effluent.

The application of membrane filtration for the polishing of wastewater treatment plant (wwtp) effluent is more and more widely used. However, fouling problems are still not well understood. In order to investigate the role of particles in dead-end ultrafiltration of wwtp-effluent, Roorda studied the influence of pre-filtrated wwtp-effluent on the filterability. In addition this research investigates the relation between the filterability of the different fractions in the wwtp-effluent and the amount of organic foulants in these fractions. The results show a relation between the filterability and supra-dissolved particles in the fractions < 0.45 and < 0.2 microm. The amount of COD, colour, proteins and polysaccharides in these fractions are found of minor importance. A significant increase in filterability is found between the fractions < 0.2 and < 0.1 microm as well as a significant decrease in amount of polysaccharides. It is suggested that an essential feature in understanding membrane fouling during ultrafiltration of wwtp-effluent is to investigate the influence of supra-dissolved particles on the filterability as well as the influence of the amount of organic foulants (total organic carbon, proteins, polysaccharides, colour and humic substances) on the reversibility.

Increasing wastewater system performance--the importance of interactions between sewerage and wastewater treatment.

The necessity to assess sewer systems and wastewater treatment plants (WWTPs) as integral parts of the wastewater system has been well known for several years and discussed in many conferences. Until recently, sewer systems and WWTPs were improved (or optimised) separately or independently, which resulted in suboptimal solutions. Nowadays, in The Netherlands as well as in other European countries, a trend can be recognised towards more integral solutions. Nevertheless, due to a lack of knowledge on the interactions between the sewer systems and the WWTPs the implementation of this way of thinking in practice takes a long time. This paper describes the results of two cases in which the interactions between sewerage and wastewater treatment are incorporated within the optimisation of a wastewater system. The first case illustrates the importance of taking the interactions into account, while the second case shows how to deal with the interactions within a wastewater system optimisation study. It is concluded that the combination of total wastewater system analysis, incorporating the interactions within the wastewater system, with efficient search algorithms is expected to be very valuable in future wastewater system optimisation studies.

Particle related fractionation and characterisation of municipal wastewater.

Several studies show that a more detailed characterisation of the particulate matter in municipal wastewater gives a better understanding and prediction of removal efficiencies of physical-chemical treatment techniques and the application of optimal chemical dosages. Such a characterisation should include the distribution of contaminants over various particle sizes. This article describes a method and results of experimental and full-scale investigations, conducted to determine how contaminants in wastewater are distributed over different particle sizes. For this purpose, particle size fractionations of wastewater influents originating from more than thirteen WWTP were carried out. One of these fractionations (WWTP Venray) is shown and interpreted in this article. First, the wastewaters were fractionated into 5 to 6 particle fractions (45, 5.0, 1.0/1.2, 0.45 and 0.1 microm) after which the fractions were analyzed for various water quality parameters like organic components, nutrients, salts, solids and turbidity. Based on the results the effects of removal of the different size fractions on design of the biological treatment and energy balance of a wastewater treatment plant can be assessed. The method also indicates whether a certain wastewater is efficiently treatable with physical-chemical pre-treatment methods. It is concluded wastewater fractionation on particle size is very useful, but that wastewater characteristics and particle size distributions should not be generalised, but have to be interpreted as indications for a certain average wastewater composition. To give more insight into the distribution of contaminants over particle size and the particle removal potential, a specific wastewater fractionation has to be carried out per WWTP.