Oxidation of carbon-silicon bonds: the dramatic advantage of strained siletanes.
Org Lett
; 5(24): 4571-3, 2003 Nov 27.
Article
en En
| MEDLINE
| ID: mdl-14627386
ABSTRACT
[reaction see text] Herein we report on the use of siletanes as substrates for the oxidation of carbon-silicon bonds. These tetraalkylsilanes are easy to handle yet susceptible to rapid ring opening and oxidation upon exposure to aqueous fluoride and peroxide. This combination of stability and reactivity presents many practical benefits, including compatibility with silicon protecting groups and electron-rich aromatic rings.
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Banco de datos:
MEDLINE
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2003
Tipo del documento:
Article
País de afiliación:
Estados Unidos