Novel three-dimensional 3d-4f microporous magnets exhibiting selective gas adsorption behavior.

Li, Cui-Jin; Lin, Zhuo-Jia; Peng, Meng-Xia; Leng, Ji-Dong; Yang, Ming-Mei; Tong, Ming-Liang

Li, Cui-Jin; Lin, Zhuo-Jia; Peng, Meng-Xia; Leng, Ji-Dong; Yang, Ming-Mei; Tong, Ming-Liang.

Afiliación

Li CJ; MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, PR China.

Chem Commun (Camb) ; (47): 6348-50, 2008 Dec 21.

Article en En | MEDLINE | ID: mdl-19048151

ABSTRACT

ABSTRACT

Three microporous Ln-Co-pyta heterometallic compounds [Ln4Co3(pyta)6(H2O)9].5H2O (Ln = Sm (1), Eu (2), Gd (3); H3pyta = 2,4,6-pyridinetricarboxylic acid) have interesting selective adsorption abilities towards H2/N2 and CO2/N2 because of size-selective effects; magnetic analysis reveals that has a ferromagnetic behavior.

Asunto(s)

Gases/química; Magnetismo; Adsorción; Modelos Moleculares; Conformación Molecular; Porosidad

Texto completo

Imprimir

XML

PubMed Links

Buscar en Google

Texto completo: 1 Banco de datos: MEDLINE Asunto principal: Gases / Magnetismo Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2008 Tipo del documento: Article

Texto completo

Imprimir

XML

PubMed Links

Buscar en Google