Silver-mediated fluorination of functionalized aryl stannanes.
J Am Chem Soc
; 131(5): 1662-3, 2009 Feb 11.
Article
en En
| MEDLINE
| ID: mdl-19191693
ABSTRACT
We report a regiospecific silver-mediated fluorination of aryl stannanes. The presented reaction can afford complex fluoroarenes from readily available phenols in three steps. The operational simplicity and the broad substrate scope of the fluorination should render this reaction a useful tool for the synthesis of milligram to gram quantities of functionalized aryl fluorides. Silver-mediated oxidative transformations of aryl nucleophiles that proceed via bimetallic redox processes are a new avenue to develop carbon-heteroatom bond formations.
Texto completo:
1
Banco de datos:
MEDLINE
Asunto principal:
Plata
/
Derivados del Benceno
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Compuestos de Estaño
/
Hidrocarburos Fluorados
Idioma:
En
Revista:
J Am Chem Soc
Año:
2009
Tipo del documento:
Article
País de afiliación:
Estados Unidos