Selective P4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides.
Chem Commun (Camb)
; 50(53): 7014-6, 2014 Jul 07.
Article
en En
| MEDLINE
| ID: mdl-24849692
ABSTRACT
The reaction of the 17e nickel(I) radical [CpNi(IDipp)] (1, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with P4 results in a nickel tetraphosphide [{CpNi(IDipp)}2(µ-η(1)η(1)-P4)] with a butterfly-P4(2-) ligand; related chalcogenides [{CpNi(IDipp)}2(µ-E2)] (E = S, Se, Te) and [{CpNi(IDipp)}2(µ-E3)] (E = S, Se) are formed with S8, Se∞ and Te∞.
Texto completo:
1
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2014
Tipo del documento:
Article
País de afiliación:
Alemania