Rhodium-Catalyzed Twofold Unsymmetrical C-H Alkenylation-Annulation/Thiolation Reaction To Access Thiobenzofurans.

Lin, Jian; Hu, Liuyu; Chen, Chao; Feng, Huijin; Yu, Yang; Yang, Yaxi; Zhou, Bing

Lin, Jian; Hu, Liuyu; Chen, Chao; Feng, Huijin; Yu, Yang; Yang, Yaxi; Zhou, Bing.

Afiliación

Lin J; Center for Supramolecular Chemistry & Catalysis and Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China.
Hu L; State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, China.
Chen C; University of Chinese Academy of Sciences, Beijing 100049, China.
Feng H; State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, China.
Yu Y; University of Chinese Academy of Sciences, Beijing 100049, China.
Yang Y; School of Chinese Materia Medica, Nanjing University of Chinese Medicine, Nanjing, Jiangsu 210023, China.
Zhou B; State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, China.

Org Lett ; 23(4): 1194-1198, 2021 02 19.

Article en En | MEDLINE | ID: mdl-33523667

RESUMEN

A Rh(III)-catalyzed twofold unsymmetrical C-H alkenylation-annulation/thiolation reaction has been developed, enabling the straightforward and efficient synthesis of various thiobenzofurans in one step. This robust protocol proceeds with a broad substrate scope and good functional group tolerance under relatively mild reaction conditions.

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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2021 Tipo del documento: Article País de afiliación: China

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