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Self-Assembly of a Pd4Cu8L8 Cage for Epoxidation of Styrene and Its Derivatives.
Zhou, Xian-Chao; Wu, Le-Xiong; Wang, Xue-Zhi; Lai, Ya-Liang; Ge, Ying-Ying; Su, Juan; Zhou, Xiao-Ping; Li, Dan.
Afiliación
  • Zhou XC; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
  • Wu LX; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
  • Wang XZ; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
  • Lai YL; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
  • Ge YY; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
  • Su J; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
  • Zhou XP; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
  • Li D; College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, People's Republic of China.
Inorg Chem ; 61(13): 5196-5200, 2022 Apr 04.
Article en En | MEDLINE | ID: mdl-35324197
ABSTRACT
Herein we report a discrete heterometallic Pd4Cu8L8 cage with a tubular structure, which was synthesized by the assembly of copper metalloligands and PdII ions in a stepwise manner. The Pd4Cu8L8 cage has been unequivocally characterized by single-crystal X-ray diffraction, electrospray ionization-mass spectroscopy, and energy dispersive spectroscopy. The cage showed excellent catalytic activity in the epoxidation of styrene and its derivatives under conditions without using additional solvent, providing potential material for catalyzing the oxidation reactions.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2022 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2022 Tipo del documento: Article