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MgI2-Catalyzed Nucleophilic Ring-Opening Reactions of Donor-Acceptor Cyclopropanes with Indoline-2-thiones.
Tang, Pan; Wei, You-Yuan; Wen, Long; Ma, Hao-Jie; Yang, Yi; Jiang, Yan.
Afiliación
  • Tang P; School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.
  • Wei YY; School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.
  • Wen L; School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.
  • Ma HJ; School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.
  • Yang Y; School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.
  • Jiang Y; School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.
J Org Chem ; 87(16): 10890-10901, 2022 Aug 19.
Article en En | MEDLINE | ID: mdl-35918174
ABSTRACT
MgI2-catalyzed nucleophilic ring-opening reactions of donor-acceptor cyclopropanes with indoline-2-thiones as easy-to-handle sulfur nucleophiles were investigated. A series of functionalized γ-indolylthio butyric acid derivatives were synthesized in good to excellent yields under mild reaction conditions. Furthermore, the thioether functionalized ring-opening products could be transformed to sulfone and methionine analogues.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2022 Tipo del documento: Article País de afiliación: China
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2022 Tipo del documento: Article País de afiliación: China