Development of a novel phosphoramidite-selenide ligand for Pd-catalyzed asymmetric allylic substitution.
Org Biomol Chem
; 20(37): 7415-7418, 2022 09 28.
Article
en En
| MEDLINE
| ID: mdl-36102881
ABSTRACT
A novel chiral P,Se-heterodonor ligand has been designed and prepared through an efficient and simple operation. This ligand can be successfully applied to Pd-catalyzed asymmetric allylic substitution with C- and N-nucleophiles, producing a diverse range of chiral allylic products in high yields and enantioselectivities (up to 99% yield and 95% ee).
Texto completo:
1
Banco de datos:
MEDLINE
Asunto principal:
Paladio
Idioma:
En
Revista:
Org Biomol Chem
Asunto de la revista:
BIOQUIMICA
/
QUIMICA
Año:
2022
Tipo del documento:
Article
País de afiliación:
China