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Sulfur-Mediated Formal Allylic C-H Cyclopropanation of α-Methylstyrenes.
Pan, Tong; Li, Pingfan.
Afiliación
  • Pan T; State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China.
  • Li P; State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China.
J Org Chem ; 88(11): 7564-7570, 2023 Jun 02.
Article en En | MEDLINE | ID: mdl-37137822
ABSTRACT
Allylic C-H cyclopropanation of α-methylstyrene and its derivatives was realized through a one-pot two-step sequence, formally converting two aliphatic C-H bonds to C-C bonds with a good yield and high diastereoselectivity, thus providing a quick entry to the synthetically useful vinyl cyclopropane structures.

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2023 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: J Org Chem Año: 2023 Tipo del documento: Article País de afiliación: China