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Induced chirality at the surface: fixation of a dynamic M/P invertible helical Co3 complex on SiO2.
Muratsugu, Satoshi; Sawaguchi, Kana; Shiraogawa, Takafumi; Chiba, Shunsuke; Sakata, Yoko; Shirai, Sora; Baba, Hiroshi; Ehara, Masahiro; Akine, Shigehisa; Tada, Mizuki.
Afiliación
  • Muratsugu S; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8602 Aichi, Japan. smuratsugu@chem.nagoya-u.ac.jp.
  • Sawaguchi K; Integrated Research Consortium on Chemical Science (IRCCS), Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8602 Aichi, Japan.
  • Shiraogawa T; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8602 Aichi, Japan. smuratsugu@chem.nagoya-u.ac.jp.
  • Chiba S; Research Center for Materials Science (RCMS), Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8602 Aichi, Japan.
  • Sakata Y; Institute for Molecular Science/School of Physical Sciences, Graduate University for Advanced Studies, Myodaiji, Okazaki, 444-8585 Aichi, Japan. ehara@ims.ac.jp.
  • Shirai S; Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Ishikawa, Japan. akine@se.kanazawa-u.ac.jp.
  • Baba H; Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Ishikawa, Japan. akine@se.kanazawa-u.ac.jp.
  • Ehara M; Nano Life Science Institute (WPI-NanoLSI), Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Ishikawa, Japan.
  • Akine S; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8602 Aichi, Japan. smuratsugu@chem.nagoya-u.ac.jp.
  • Tada M; Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8602 Aichi, Japan. smuratsugu@chem.nagoya-u.ac.jp.
Chem Commun (Camb) ; 60(15): 2094-2097, 2024 Feb 15.
Article en En | MEDLINE | ID: mdl-38294205
ABSTRACT
Dynamic M/P invertible helicity was successfully induced at a SiO2 surface immobilized with a dynamic helical trinuclear cobalt complex, [LCo3(NHMe2)6](OTf)3, using chiral ((R) or (S))-1-phenylethylamine. Solid-state CD spectra and theoretical calculations suggested that the fixation of the M/P helical complex on the surface via coordination interactions was the key factor of the induced chirality at the surface.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Japón
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: Japón