Rhodium(III)-Catalyzed Oxidative 1,3-Aryl Migration of α-Aryl Allylic Alcohols.
J Org Chem
; 89(6): 3684-3695, 2024 Mar 15.
Article
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| MEDLINE
| ID: mdl-38394358
ABSTRACT
A Rh(III)-catalyzed oxidative 1,3-aryl migration of α-arylallylic alcohols via Csp2-Csp3 σ bond activation has been developed. This method provides an efficient strategy to allow for allylic alcohol-based skeleton rearrangement, in which various secondary and tertiary α-arylallylic alcohols are rapidly converted to ß-aryl-α, ß-unsaturated ketones and aldehydes.
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Banco de datos:
MEDLINE
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En
Revista:
J Org Chem
Año:
2024
Tipo del documento:
Article
País de afiliación:
China