Multiple Functions of l-Thioproline in the Synthesis of Chiral Metal Bromides Showing Second-Harmonic-Generation Responses.
Inorg Chem
; 63(18): 8013-8017, 2024 May 06.
Article
en En
| MEDLINE
| ID: mdl-38652668
ABSTRACT
Three new homochiral metal bromides, namely, (l-Htp)2Cu2Br4 (1), (l-Htp)(l-tp)CdBr3 (2), and (l-tp)2ZnBr2 (3), were prepared using l-thioproline as the chiral template. These compounds feature dimeric, chainlike, and monomeric structures. Their second-harmonic-generation (SHG) efficiencies are 0.1, 0.3, and 2.0 times that of KH2PO4, respectively. Density functional theory calculations were performed to reveal the origin of the SHG response of compound 3.
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Banco de datos:
MEDLINE
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En
Revista:
Inorg Chem
Año:
2024
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Article
País de afiliación:
China