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Electrochemical ring-opening carboxylation of cyclic carbonate with carbon dioxide.
Tao, Li; Wang, He; Liu, Xiao-Fei; Ren, Wei-Min; Lu, Xiao-Bing; Zhang, Wen-Zhen.
Afiliación
  • Tao L; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, China. zhangwz@dlut.edu.cn.
  • Wang H; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, China. zhangwz@dlut.edu.cn.
  • Liu XF; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, China. zhangwz@dlut.edu.cn.
  • Ren WM; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, China. zhangwz@dlut.edu.cn.
  • Lu XB; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, China. zhangwz@dlut.edu.cn.
  • Zhang WZ; State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Dalian University of Technology, Dalian, 116024, China. zhangwz@dlut.edu.cn.
Chem Commun (Camb) ; 60(44): 5735-5738, 2024 May 28.
Article en En | MEDLINE | ID: mdl-38742637
ABSTRACT
Electroreductive ring-opening carboxylation of styrene carbonates with CO2 to achieve dicarboxylic acids and/or ß-hydroxy acids has been developed via the selective cleavage of the C(sp3)-O bond in cyclic carbonates. The product selectivity is probably determined by the stability and reactivity of the key benzylic radical and carbanion intermediate.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China