Investigation of heavy metal contamination and associated health risks in groundwater sources of southwestern Punjab, India.

Human body exposure to various toxic and non-toxic heavy metals in groundwater is a significant health concern, especially in developing countries. The present study was planned and carried out to appraise the potential health risks of eight heavy metals (Mn, Co, Cu, As, Se, Cd, Hg, and Pb) in different water sources of the Mansa and Muktsar districts of Punjab. The measurements of heavy metals were performed using the inductively coupled plasma mass spectrometry (ICPMS) technique. The health (carcinogenic and non-carcinogenic) risks and doses (ingestion and dermal) associated with exposure to heavy metals in water were estimated from the measured concentrations using USEPA guidelines. The average concentrations of heavy metals were observed in the order of Mn (13.93) > Cu (13.12) > Se (4.14) > As (3.28) > Hg (3.27) > Pb (1.29) > Co (0.20) > Cd (0.10) µg L-1. The results show that the Hg, Pb, As, and Se concentrations are above the guideline values of the World Health Organization (WHO) in 10.34%, 3.45%, 6.90%, and 6.90% locations, respectively. The high values of these heavy metals may be due to geogenic anthropogenic activities. The hazard quotients (non-carcinogenic risk) for ingestion and dermal exposures were observed in the range of 0.32-3.79 and 8.05 × 10-6-1.34 × 10-4, respectively. On the other hand, the carcinogenic health risks due to ingestion and dermal exposure were observed to be 0.02-0.38 and 6.67 × 10-8-1.15 × 10-6, respectively. The results of this study will be helpful to the drinking water supplying agencies, water resource development authorities, etc.

Occurrences, sources and health hazard estimation of potentially toxic elements in the groundwater of Garhwal Himalaya, India.

High concentrations of potentially toxic elements (PTEs) in potable water can cause severe human health disorders. Present study examined the fitness of groundwater for drinking purpose based on the occurrence of nine PTEs in a heavy pilgrim and tourist influx region of the Garhwal Himalaya, India. The concentrations of analyzed PTEs in groundwater were observed in the order of Zn > Mn > As > Al > Cu > Cr > Se > Pb > Cd. Apart from Mn and As, other PTEs were within the corresponding guideline values. Spatial maps were produced to visualize the distribution of the PTEs in the area. Estimated water pollution indices and non-carcinogenic risk indicated that the investigated groundwater is safe for drinking purpose, as the hazard index was < 1 for all the water samples. Assessment of the cancer risk of Cr, As, Cd, and Pb also indicated low health risks associated with groundwater use, as the values were within the acceptable range of ≤ 1 × 10-6 to 1 × 10-4. Multivariate statistical analyses were used to describe the various possible geogenic and anthropogenic sources of the PTEs in the groundwater resources although the contamination levels of the PTEs were found to pose no serious health risk. However, the present study recommends to stop the discharge of untreated wastewater and also to establish cost-effective as well as efficient water treatment facility nearby the study area. Present work's findings are vital as they may protect the health of the massive population from contaminated water consumption. Moreover, it can help the researchers, governing authorities and water supplying agencies to take prompt and appropriate decisions for water security.

A systematic study on occurrence, risk estimation and health implications of heavy metals in potable water from different sources of Garhwal Himalaya, India.

The occurrence of heavy metals (HMs) in drinking water has been a critical water quality concern for a long time and can compromise its aesthetic value to the larger extent. Chronic exposure of human beings to these toxic and non-toxic HMs through water ingestion can result in significant health risks. To assess these associated health risks, the present study was planned, designed and carried out for analyses of nine HMs namely, Al, Cr, Mn, Co, Ni, Cu, Zn, Cd and Pb in the potable water samples collected from different sources located across the Mandakini valley of Garhwal Himalaya, India using Inductively Coupled Plasma Mass Spectrometry. The measured values of Al, Cr, Mn, Co, Ni, Cu, Zn, Cd and Pb were found in the range of BDL-27.4 µg l-1, 0.26-4.5 µg l-1, BDL-139 µg l-1, 0.02-0.9 µg l-1, 0.4-5.5 µg l-1, 0.07-9.2 µg l-1, BDL-4164 µg l-1, BDL-0.8 µg l-1, and BDL-11.2 µg l-1, respectively. The observed values of analyzed HMs except Zn and Pb were found below the reference values prescribed by the WHO, USEPA and BIS. In addition, Zn concentration exceeded its maximum permissible limit (4000 µg l-1) recommended by WHO for infants at one station only. The observed indices show that there are no health risks from HMs contamination via drinking water in the region. Moreover, the estimated hazard quotients for children and adults also revealed no potential health risks. The results of present study will be useful as baseline data for state and national regulatory agencies.