Electrokinetic ion transport and fluid flow in a pH-regulated polymer-grafted nanochannel filled with power-law fluid.

In this article, we have discussed extensively electrokinetic ion transport and fluid flow through a slit polymer-grafted nanochannel filled with power-law fluid. The rigid walls of the channel are coated with the ion and fluid penetrable polymer layer containing a pH-regulated zwitterionic functional group (e.g., succinoglycan). The mathematical model is based on the non-linear Poisson-Boltzmann equation for electric double layer potential and the flow field within the polymer layer is governed by a modified Darcy-Brinkman equation; the Cauchy momentum equation governs the fluid flow outside of the polymer layer along with the equation of continuity for incompressible fluid. In order to consider a wide range of pertinent parameters, we adopt a finite difference based numerical tool to solve the coupled set of governing equations. We have analyzed several interesting features of electrokinetic transport phenomena through such a polymer-grafted nanochannel for a wide range of electrostatic and hydrodynamic properties of the polymer layer, parameters describing the non-Newtonian rheology of the background fluid, and the pH and concentration of the bulk electrolyte. In addition, we have also illustrated the ionic current across the undertaken nanochannel and observed that it can be either cation selective, anion selective or non-selective, depending on the critical choice of the pertinent parameters.

Effect of induced electric field on migration of a charged porous particle.

The effect of ambient fluid flow on a charged porous spherical particle suspended in an aqueous medium is analyzed. The porous particle is ion permeable and fluid penetrable. The induced electric field due to the polarization of the particle's electric double layer and counterion condensation leads to a hindrance effect on particle migration by producing an electric force. The influence of this retardation force on the hydrodynamics of the particle is studied through the Nernst-Planck equations, which are coupled with the Stokes-Brinkman equation. The interactions of the double-layer polarization, shielding effect, electroosmosis of unbalanced ions and fluid convection are analyzed. The settling velocity and fluid collection efficiency of the charged aggregate is determined. We have studied the electrokinetics for a wide range of fixed charge density and permeability of the particle with no assumption made on the thickness of the double layer relative to the dimension of the particle.