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Angew Chem Int Ed Engl
; 62(23): e202301611, 2023 Jun 05.
Article
in English
| MEDLINE
| ID: mdl-36973914
ABSTRACT
Low-valent metal-organic frameworks (LVMOFs) and related materials have gained interest due to their potential applications in heterogeneous catalysis. However, of the few LVMOFs that have been reported, none have shown catalytic activity. Herein, a low-valent metal-organic material constructed from phosphine linkers and IrI nodes is reported. This material is effectively a crystalline, insoluble analogue of Vaska's complex. As such, the material reversibly binds O2 and catalyzes the reductive formation of enamines from amides.