Nanobiocomposite Polymer as a Filter Nanosponge for Wastewater Treatment.

A multifunctional nanobiocomposite polymer was developed in this study through a cross-linking polymerization of cyclodextrin with phosphorylated multi-walled carbon nanotubes followed by sol-gel to incorporate TiO2 and Ag nanoparticles. This work's novelty was to prove that the developed nanobiocomposite polymer is a potential filter nanosponge capable of removing organic, inorganic, and microorganisms' pollutants from wastewater samples. The synthesized multifunctional nanobiocomposite polymer was characterized using a range of spectroscopy and electron microscopy techniques. Fourier-transform infrared (FTIR) confirmed the presence of oxygen-containing groups on the developed nanobiocomposite polymer and carbamate linkage (NH(CO)) distinctive peak at around 1645 cm-1, which is evidence that the polymerization reaction was successful. The scanning electron microscopy (SEM) image shows that the developed nanobiocomposite polymer has a rough surface. The Dubinin-Radushkevich and the pseudo-second-order kinetic models best described the adsorption mechanism of Co2+ and TCE's onto pMWCNT/CD/TiO2-Ag. The efficacy of the developed nanobiocomposite polymer to act as disinfectant material in an environmental media (e.g., sewage wastewater sample) compared to the enriched media (e.g., nutrient Muller Hinton broth) was investigated. From the results obtained, in an environmental media, pMWCNT/CD/TiO2-Ag nanobiocomposite polymer can alter the bacteria's metabolic process by inhibiting the growth and killing the bacteria, whereas, in enriched media, the bacteria's growth was retarded.

A Review on Conventional and Advanced Methods for Nanotoxicology Evaluation of Engineered Nanomaterials.

Nanotechnology can be defined as the field of science and technology that studies material at nanoscale (1-100 nm). These nanomaterials, especially carbon nanostructure-based composites and biopolymer-based nanocomposites, exhibit excellent chemical, physical, mechanical, electrical, and many other properties beneficial for their application in many consumer products (e.g., industrial, food, pharmaceutical, and medical). The current literature reports that the increased exposure of humans to nanomaterials could toxicologically affect their environment. Hence, this paper aims to present a review on the possible nanotoxicology assays that can be used to evaluate the toxicity of engineered nanomaterials. The different ways humans are exposed to nanomaterials are discussed, and the recent toxicity evaluation approaches of these nanomaterials are critically assessed.

Chitosan nanocomposites for water treatment by fixed-bed continuous flow column adsorption: A review.

Nowadays, access to clean water sources worldwide and particularly in Southern Africa is inadequate because of its pollution by organic, inorganic, and microorganism contaminants. A range of conventional water treatment techniques has been used to resolve the problem. However, these methods are currently facing the confronts posed by new emerging contaminants. Therefore, there is a need to develop simple and lower cost-effective water purification methods that use recyclable bio-based natural polymers such as chitosan modified with nanomaterials. These novel functional chitosan-based nanomaterials have been proven to effectively eliminate the different environmental pollutants from wastewater to acceptable levels. This paper aims to present a review of the recent development of functional chitosan modified with carbon nanostructured and inorganic nanoparticles. Their application as biosorbents in fixed-bed continuous flow column adsorption for water purification is also discussed.

Recent development in antimicrobial activity of biopolymer-inorganic nanoparticle composites with water disinfection potential: a comprehensive review.

Nowadays, water-borne diseases including hepatitis remain the critical health challenge due to the inadequate supply of potable and safe water for human activities. The major cause is that the pathogenic microorganisms causing diseases have developed resistance against common techniques used by sewage water treatment plants for water disinfection. Therefore, there is a need to improve these conventional water treatment techniques by taking into consideration the application of nanotechnology for wastewater purification. The main aim of this paper is to provide a review on the synthesis of biopolymer-inorganic nanoparticle composites (BINCs), their used as antimicrobial compounds for water disinfection, as well as to elaborate on their antimicrobial mechanism of action. The microbial properties affecting the activity of antimicrobial compounds are also evaluated.