The Composition and Chemistry of Titan's Atmosphere.

In this review I summarize the current state of knowledge about the composition of Titan's atmosphere and our current understanding of the suggested chemistry that leads to that observed composition. I begin with our present knowledge of the atmospheric composition, garnered from a variety of measurements including Cassini-Huygens, the Atacama Large Millimeter/submillimeter Array, and other ground- and space-based telescopes. This review focuses on the typical vertical profiles of gases at low latitudes rather than global and temporal variations. The main body of the review presents a chemical description of how complex molecules are believed to arise from simpler species, considering all known "stable" molecules-those that have been uniquely identified in the neutral atmosphere. The last section of the review is devoted to the gaps in our present knowledge of Titan's chemical composition and how further work may fill those gaps.

Organic Input to Titan's Subsurface Ocean Through Impact Cratering.

Titan has an organic-rich atmosphere and surface with a subsurface liquid water ocean that may represent a habitable environment. In this work, we determined the amount of organic material that can be delivered from Titan's surface to its ocean through impact cratering. We assumed that Titan's craters produce impact melt deposits composed of liquid water that can founder in its lower-density ice crust and estimated the amount of organic molecules that could be incorporated into these melt lenses. We used known yields for HCN and Titan haze hydrolysis to determine the amount of glycine produced in the melt lenses and found a range of possible flux rates of glycine from the surface to the subsurface ocean. These ranged from 0 to 1011 mol/Gyr for HCN hydrolysis and from 0 to 1014 mol/Gyr for haze hydrolysis. These fluxes suggest an upper limit for biomass productivity of ∼103 kgC/year from a glycine fermentation metabolism. This upper limit is significantly less than recent estimates of the hypothetical biomass production supported by Enceladus's subsurface ocean. Unless biologically available compounds can be sourced from Titan's interior, or be delivered from the surface by other mechanisms, our calculations suggest that even the most organic-rich ocean world in the Solar System may not be able to support a large biosphere.

Cassini spacecraft reveals global energy imbalance of saturn.

The global energy budget is pivotal to understanding planetary evolution and climate behaviors. Assessing the energy budget of giant planets, particularly those with large seasonal cycles, however, remains a challenge without long-term observations. Evolution models of Saturn cannot explain its estimated Bond albedo and internal heat flux, mainly because previous estimates were based on limited observations. Here, we analyze the long-term observations recorded by the Cassini spacecraft and find notably higher Bond albedo (0.41 ± 0.02) and internal heat flux (2.84 ± 0.20 Wm-2) values than previous estimates. Furthermore, Saturn's global energy budget is not in a steady state and exhibits significant dynamical imbalances. The global radiant energy deficit at the top of the atmosphere, indicative of the planetary cooling of Saturn, reveals remarkable seasonal fluctuations with a magnitude of 16.0 ± 4.2%. Further analysis of the energy budget of the upper atmosphere including the internal heat suggests seasonal energy imbalances at both global and hemispheric scales, contributing to the development of giant convective storms on Saturn. Similar seasonal variabilities of planetary cooling and energy imbalance exist in other giant planets within and beyond the Solar System, a prospect currently overlooked in existing evolutional and atmospheric models.

Atacama Large Aperture Submillimeter Telescope (AtLAST) science: Planetary and cometary atmospheres.

The study of planets and small bodies within our Solar System is fundamental for understanding the formation and evolution of the Earth and other planets. Compositional and meteorological studies of the giant planets provide a foundation for understanding the nature of the most commonly observed exoplanets, while spectroscopic observations of the atmospheres of terrestrial planets, moons, and comets provide insights into the past and present-day habitability of planetary environments, and the availability of the chemical ingredients for life. While prior and existing (sub)millimeter observations have led to major advances in these areas, progress is hindered by limitations in the dynamic range, spatial and temporal coverage, as well as sensitivity of existing telescopes and interferometers. Here, we summarize some of the key planetary science use cases that factor into the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST), a proposed 50-m class single dish facility: (1) to more fully characterize planetary wind fields and atmospheric thermal structures, (2) to measure the compositions of icy moon atmospheres and plumes, (3) to obtain detections of new, astrobiologically relevant gases and perform isotopic surveys of comets, and (4) to perform synergistic, temporally-resolved measurements in support of dedicated interplanetary space missions. The improved spatial coverage (several arcminutes), resolution (~ 1.2'' - 12''), bandwidth (several tens of GHz), dynamic range (~ 10 5) and sensitivity (~ 1 mK km s -1) required by these science cases would enable new insights into the chemistry and physics of planetary environments, the origins of prebiotic molecules and the habitability of planetary systems in general.

Our present understanding of what planets and comets are made of, and how their atmospheres move and change, has been greatly influenced by observations using existing and prior telescopes operating at wavelengths in the millimeter/submillimeter range (between the radio and infrared parts of the electromagnetic spectrum), yet major gaps exist in our knowledge of these diverse phenomena. Here, we describe the need for a new telescope capable of simultaneously observing features on very large and very small scales, and covering a very large spread of intrinsic brightness, in planets and comets. Such a telescope is required for mapping storms on giant planets, measuring the compositions of the atmospheres and plumes of icy moons, detecting new molecules in comets and planetary atmospheres, and to act as a complement for measurements by current and future interplanetary spacecraft missions. We discuss the limitations of currently-available millimeter/submillimeter telescopes, and summarize the requirements and applications of a new and larger, more sensitive facility operating at these wavelengths: the Atacama Large Aperture Submillimeter Telescope (AtLAST).