Enhanced Adsorption of Hexavalent Chromium from Aqueous Solutions by Iron- manganese Modified Cedarwood Biochar: Synthesis, Performance, Mechanism, and Variables.

Three modified biochar (Cunninghamia lanceolata) with iron and manganese elementals (FMBCs) were successfully prepared and used to remove hexavalent chromium (Cr(VI)) from aqueous solutions. The biochar before and after decoration were characterized by advanced instruments. The adsorption capacities of modified biochar in different Cr(VI) (20 mg·L- 1, 1 mg·L- 1) solutions were 4868.28 mg·kg- 1 and 300 mg·kg- 1. The Cr(VI) removal was highest at pH 2. The possible adsorption was considered to be ion exchange adsorption, chemisorption, and electrostatic attraction. Meanwhile, interfering ions are conducive to increasing the adsorption content. FMBCs prepared at different temperatures showed different characteristics, single-use and cycle-use performance, and high and low concentration removal superiority. The result indicated that FMBCs had a promising potential as an adsorbent to remove toxic and harmful Cr(VI) from aqueous solutions.

Occurrence and behavior of per- and polyfluoroalkyl substances and conversion of oxidizable precursors in the waters of coastal tourist resorts in China.

Per- and polyfluorolkyl substances (PFAS) were measured in the water and fish from 20 coastal tourist resorts in China, to investigate their sources, seasonal differences, and bioconcentration. An oxidative method with hydroxyl radicals was used to extract potential perfluoroalkyl acid (PFAA) precursors in the water of resorts. The results indicated that the total concentrations of target chemicals (i.e., ΣPFAS) in the original water were 59.4-138, 32.7-77.2, and 14.6-29.9 ng L-1 in December, April, and August, respectively. C4-C10 perfluorocarboxlate (PFCA) and perfluorooctane sulfonate (PFOS) accounted for 67%-92% of the ΣPFAS contents in all water samples. The PFAS concentrations in the muscles and liver of fish were 16.0-162 ng g-1 ww and 186-1240 ng g-1 ww, respectively. The dominant compounds were perfluorobutanoate acid (PFBA) and PFOS in the water, and perfluorooctanoic acid (PFOA) and PFOS in fish tissues. High bioconcentration were observed for PFCA (C ≥ 8) and perfluorosulfonate (PFSA, C ≥ 6). After oxidative conversion, the water exhibited a noticeable increase in the ΣPFAS value. Precursors that generated C4-C9 PFCA were more prevalent than precursors that generated other PFCA upon oxidation. The concentration of C8-based precursor was higher than that of C6-based precursor in wet and dry seasons. This study is the first to apply an oxidative method to investigate PFAS pollution in the water of coastal tourist resorts. The results verified that PFAA precursors exist in the water of coastal tourist resorts, and more attention should be given to the existence of PFAA precursors and the safety of water in coastal tourist resorts.

Occurrence, spatiotemporal distribution patterns,partitioning and risk assessments of multiple pesticide residues in typical estuarine water environments in eastern China.

The low terrain and the prosperous agriculture in the east of China, have caused the accumulation of pesticide residues in the estuaries. Therefore, this study analyzed the spatiotemporal distribution and partition tendency of 106 pesticides based on their abundance, frequencies, and concentrations in the aquatic environment of 16 river estuaries in 7 major basins in the eastern China by using solid-phase extraction (SPE) with high-performance liquid chromatography tandem mass spectrometry (HPLC‒MS/MS) and gas chromatography tandem mass spectrometry (GC‒MS/MS). In addition, potential risk of multiple pesticides was also evaluated. The results showed that herbicides were the dominant pesticide type, while triazines were the predominate substance group of pesticide. In addition, triadimenol, vinclozolin, diethylatrazine, prometryn, thiamethoxam, atrazine, and metalachlor were the major pesticides in the water, while prometryn, metalachlor, and atrazine were the main pesticides in the sediment. The average total concentration of pesticide was 751.15 ng/L in the dry season, 651.17 ng/L in the wet season, and 617.37 ng/L in the normal season, respectively. The estuaries of the Huai River Basin, the Yangtze River Basin, the Hai River Basin, and the Yellow River Basin have been affected by the low pollution treatment efficiency, weak infrastructure, and agricultural/non-agricultural activities in eastern China, resulting in relatively serious pesticide pollution. The estuaries of Huaihe River, Yangtze River, Xiaoqing River, and Luanhe River had large pesticide abundance and comparatively severe pesticide pollution, while the estuaries of Tuhai River and Haihe River had heavy pesticide contamination in the sediment, which might be induced by historical sedimentary factors. The log KOC values showed that except for thioketone, other pesticides were relatively stable due to the adsorption by sediment. The ecological risk assessment results indicated that insecticides had a high risk. Teenagers were the most severely affected by the noncarcinogenic risk of pesticides, while adults were mostly affected by the carcinogenic risk of pesticides. Therefore, pesticide hazards in the water environment of estuaries in eastern China needs to be further close supervision.

Removal of antimonite and antimonate in aqueous solution by mugwort biochar modified by Acidithiobacillus ferrooxidans after pyrolysis.

In the research, iron oxides-biochar composites (ALBC) were prepared from pristine biochar modified by Acidithiobacillus ferrooxidans (A. ferrooxidans) and pyrolyzed at 500 °C and 700 °C in order to remove antimonite (Sb(III)) and antimonate (Sb(V)) from water. The results indicated that biochar prepared at 500 °C and 700 °C (ALBC500 and ALBC700) were loaded with Fe2O3 and Fe3O4, respectively. In bacterial modification systems, ferrous iron and total iron concentrations decreased continuously. The pH values of bacterial modification systems including ALBC500 increased first and then decreased to a stable state, while the pH values of bacterial modification systems with ALBC700 continued to decrease. The bacterial modification systems can facilitate the formation of more jarosites by A. ferrooxidans. ALBC500 had optimal adsorbing capacities for Sb(III) (18.81 mg·g-1) and Sb(V) (14.64 mg·g-1). The main mechanisms of Sb(III) and Sb(V) adsorption by ALBC were electrostatic interaction and pore filling.

Spatiotemporal variations and bioaccumulation of per- and polyfluoroalkyl substances and oxidative conversion of precursors in shallow lake water.

Per- and polyfluoroalkyl substances (PFAS) in water and fish from Nansi Lake, Chian and in inflowing tributaries and nearby sewage treatment plants (STPs) were determined to evaluate their distribution and bioaccumulation. The potential precursors of perfluoroalkyl acid (PFAA) present in the water were converted via hydroxyl radical oxidation. Over 3 seasons, the average concentration ranges of the 15 PFAA (∑15PFAA) concentrations in Nansi Lake, inflowing tributaries, and STPs were 22.8-70.3, 19.5-43.5, and 84.1-129 ng L-1, respectively. Perfluorooctanoic acid, perfluorooctane sulfonate (PFOS), and short-chain PFAA (perfluorocarboxlate acid <8, perfluorosulfonate acids <6) were present in high concentrations in the lake and tributaries. PFAA concentration was the lowest during the wet season and the highest during the dry season. Moreover, PFAA precursors were converted to perfluorocarboxlate acid. The concentration of C8-based precursors was higher than that of the C6-based precursors in the lake and tributaries. The concentration of PFAA in the fish liver was higher than that in fish muscles, and PFOS was the dominant chemical present in fish. Potential risk assessment based on Environment Quality Standard revealed heavy PFOS contamination in the fish. Thus, the water of Nansi Lake was heavily polluted by PFAS.