Negative magnetostrictive paper formed by dispersing CoFe2O4 particles in cellulose nanofibrils.

Polymers are often combined with magnetostrictive materials to enhance their toughness. This study reports a cellulose nanofibril (CNF)-based composite paper containing dispersed CoFe2O4 particles (CNF-CoFe2O4). Besides imparting magnetization and magnetostriction, the incorporation of CoFe2O4 particles decreased the ultimate tensile strength and increased the fracture elongation of the CNF-CoFe2O4 composite paper. CNF was responsible for the tensile properties of CNF-CoFe2O4 composite paper. Consequently, the magnetic and magnetostrictive properties and tensile properties of CNF-CoFe2O4 composite paper can be controlled by changing the mixture ratio of CNF and CoFe2O4 particles.

Variation of the Tensile Properties of Basalt-Fiber-Reinforced Polybutylene Succinate Matrix Composites during Microbial Degradation.

Little is known about how the strength of biodegradable polymers changes during decomposition. This study investigated the changes in the tensile properties of polybutylene succinate (PBS) and basalt-fiber (BF)-reinforced PBS (PBS-BF) composite sheets during degradation in bacterial solutions. Seven days after the start of the experiment, the elongation at break of the PBS specimens decreased significantly, and the PBS-BF composite specimens were characterized by barely any change in ultimate tensile strength (UTS) after immersion in the bacteria-free medium for 7 and 56 days. Meanwhile, when immersed in the bacterial solution, the UTS of the PBS-BF composite specimens showed a tendency to decrease after 7 days. After 56 days, the UTS decreased to about half of its value immediately after fabrication. The degradation of the material was attributed to infiltration of the bacterial solution into structurally weak areas, causing decomposition throughout the material.

Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites.

Cellulose acetate (CA) is widely used as an alternative to conventional plastics because of the minor environmental impact of its decomposition cycle. This study synthesized five-layer environmentally friendly composites from CA bioplastic and basalt fibers (BFs) to produce a high-strength marine-biodegradable polymer. Maleic anhydride-grafted polypropylene (PP-g-MAH) was mixed with CA as a surface-active agent (SAA) to understand the effect of surface treatment on the mechanical properties of the composite. Tensile tests and scanning electron microscopy were conducted to observe the fracture surfaces. The ultimate tensile strength (UTS) of the BF/CA composite increased by approximately a factor of 4 after adding 11 vol.% unidirectional BF. When the SAA was added, the UTS of the composite with 11 vol.% BF was multiplied by a factor of about 7, which indicates that the surface treatment has a significant positive effect on the mechanical properties. However, the improvement is not apparent when the added BFs are in a plain weave with a vertical orientation. A photodecomposition experiment was then conducted by adding TiO2. Observing the UTS changes of the CA and BF/CA composites, the effect of the photocatalyst on the decomposition of the materials was explored.