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J Pharm Biomed Anal ; 43(4): 1376-81, 2007 Mar 12.
Artículo en Inglés | MEDLINE | ID: mdl-17207600

RESUMEN

This work describes the construction and evaluation of lactate sol-gel biosensors to accomplish the determination of lactate in pharmaceutical products. Lactate oxidase was incorporated in a porous sol-gel film placed onto a platinum-based electrode. Acid and basic catalysis were assessed. When coupled to a sequential injection system (SIA) the biosensor, based on (3-aminopropyl)trimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyl-trimethoxysilane, deionised water, polyethylene glycol 6000 and acid catalyst, presented a range of linearity of 5x10(-5) to 5x10(-3)M. The analytical usefulness of the developed biosensor was evaluated through analysis of commercial pharmaceutical products containing lactate with a sampling rate of 40 samples h(-1). The enzyme remained active for at least 30 days, enabling about 700 determinations without sensitivity decrease.


Asunto(s)
Técnicas Biosensibles/métodos , Enzimas Inmovilizadas/análisis , Ácido Láctico/análisis , Transición de Fase , Técnicas Biosensibles/instrumentación , Electroquímica , Enzimas Inmovilizadas/química , Geles , Cinética , Ácido Láctico/química , Preparaciones Farmacéuticas/análisis , Preparaciones Farmacéuticas/química
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