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1.
J Nanosci Nanotechnol ; 12(6): 4984-90, 2012 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-22905563

RESUMEN

Gas turbine's efficiency improves as operating temperature is increased. For this reason, metallic components used in turbine engines, for propulsion and power generation, are protected by thermal barrier coatings (TBC). Laser glazing has been used to enhance the oxidation and corrosion resistance of thermally sprayed TBC, but there is no information about the effect of this treatment on the tribological performance. ZrO2(CaO) top coat and NiAIMo bond coating were flame sprayed onto an AlSI 1045 carbon steel. The top coat was laser remelted and a densified ceramic layer was induced in the top surface of the ceramic coating. Both, the as sprayed and the laser remelted top coatings, were formed by cubic ZrO2 with some tetragonal precipitates. The grain size was reduced by the laser treatment. The mechanical properties and the local wear rate were evaluated by depth sensing indentation and scratch tests respectively. The nanoscale wear behaviour was always improved by the laser treatment.


Asunto(s)
Cerámica/química , Cerámica/efectos de la radiación , Rayos Láser , Nanoestructuras/química , Nanoestructuras/ultraestructura , Protección Radiológica/métodos , Calor , Ensayo de Materiales , Nanoestructuras/efectos de la radiación , Tamaño de la Partícula , Conductividad Térmica
2.
J Nanosci Nanotechnol ; 11(10): 8724-9, 2011 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-22400250

RESUMEN

Thermal barrier coatings are extensively used to protect metallic components in applications where the operating conditions include aggressive environment at high temperatures. These coatings are usually processed by thermal spraying techniques and the resulting microstructure includes thin and large splats, associated with the deposition of individual droplets, with porosity between splats. This porosity reduces the oxidation and corrosion resistance favouring the entrance of aggressive species during service. To overcome this limitation, the top coat could be modified by laser glazing reducing surface roughness and sealing open porosity. ZrO2(Y2O3) top coat and NiCrAlY bond coating were air plasma sprayed onto an Inconel 600 Ni base alloy. The top coat was laser remelted and a densified ceramic layer was induced in the top surface of the ceramic coating. This layer inhibited the ingress of aggressive species and delayed bond coat oxidation.

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