P(III)-Mediated Formal Reductive N-H Bond Insertion Reaction of Hydrazones to α-Keto Esters.

A diazo-, metal-, and base-free multi-substituted hydrazone synthesis via a formal reductive N-H bond insertion reactions of hydrazones to α-keto esters has been developed. The protocol features a broad substrate scope and good functional group tolerance, providing N-H bond insertion products in moderate to excellent yields. Moreover, P(III)-mediated N-H functionalization of pharmaceutical containing hydrazone moiety was also successfully achieved.

A barrier to radial oxygen loss helps the root system cope with waterlogging-induced hypoxia.

Internal aeration is crucial for root growth under waterlogged conditions. Many wetland plants have a structural barrier that impedes oxygen leakage from the basal part of roots called a radial oxygen loss (ROL) barrier. ROL barriers reduce the loss of oxygen transported via the aerenchyma to the root tips, enabling long-distance oxygen transport for cell respiration at the root tip. Because the root tip does not have an ROL barrier, some of the transferred oxygen is released into the waterlogged soil, where it oxidizes and detoxifies toxic substances (e.g., sulfate and Fe2+) around the root tip. ROL barriers are located at the outer part of roots (OPRs). Their main component is thought to be suberin. Suberin deposits may block the entry of potentially toxic compounds in highly reduced soils. The amount of ROL from the roots depends on the strength of the ROL barrier, the length of the roots, and environmental conditions, which causes spatiotemporal changes in the root system's oxidization pattern. We summarize recent achievements in understanding how ROL barrier formation is regulated and discuss opportunities for breeding waterlogging-tolerant crops.

Stress monitoring capability of magnetostrictive Fe-Co fiber/glass fiber reinforced polymer composites under four-point bending.

Many structural health monitoring (SHM) techniques have been investigated for damage detection in woven glass fiber reinforced polymer (GFRP) laminates. Recently, the GFRP composites integrated with sensors have received attention because the composite material can transmit information about the structural condition during operation. Magnetostrictive materials are considered as feasible candidates to realize the contactless SHM techniques by exploiting the Villari effect, but the theoretical modeling to correlate a magnetostrictive response with structural conditions is a critical issue. In this study, the analytical procedure considering the mechanics of materials and electromagnetism was proposed to model the magnetic induction by the Villari effect of magnetostrictive GFRP laminates under bending. The magnetostrictive Fe-Co fiber/GFRP composites were then developed, and the four-point bending tests were carried out to evaluate the fabricated composites' stress monitoring capability. The magnetic flux density behavior corresponded to the bending stress fluctuation. The maximum magnetic flux density change was 70.7 mT subjected to the peak bending stress of 158 MPa. The analytical solutions showed reasonable agreement with the experimental results. The applied stress and measured magnetic flux density were correlated by the theoretical models. Thus, these results suggest an important step in realizing the novel contactless SHM technique utilizing magnetostrictive materials.