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Ammonia recovery from wastewater has positive environmental benefits, avoiding eutrophication and reducing production energy consumption, which is one of the most effective ways to manage nutrients in wastewater. Specifically, ammonia recovery by membrane distillation has been gradually adopted due to its excellent separation properties for volatile substances. However, the global optimization of direct contact membrane distillation (DCMD) operating parameters to maximize ammonia recovery efficiency (ARE) has not been attempted. In this work, three key operating factors affecting ammonia recovery, i.e., feed ammonia concentration, feed pH, and DCMD running time, were identified from eight factors, by a two-level Plackett-Burman Design (PBD). Subsequently, Box-Behnken design (BBD) under the response surface methodology (RSM) was used to model and optimize the significant operating parameters affecting the recovery of ammonia though DCMD identified by PBD and statistically verified by analysis of variance (ANOVA). Results showed that the model had a high coefficient of determination value (R2 = 0.99), and the interaction between NH4Cl concentration and feed pH had a significant effect on ARE. The optimal operating parameters of DCMD as follows: NH4Cl concentration of 0.46 g/L, feed pH of 10.6, DCMD running time of 11.3 h, and the maximum value of ARE was 98.46%. Under the optimized conditions, ARE reached up to 98.72%, which matched the predicted value and verified the validity and reliability of the model for the optimization of ammonia recovery by DCMD process.
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Amoníaco , Destilación , Aguas Residuales , Amoníaco/química , Destilación/métodos , Aguas Residuales/química , Eliminación de Residuos Líquidos/métodos , Modelos Teóricos , Concentración de Iones de Hidrógeno , Membranas ArtificialesRESUMEN
Limited triple-phase boundaries arising from the accumulation of solid discharge product(s) in solid-state cathodes (SSCs) pose a challenge to high-property solid-state lithium-oxygen batteries (SSLOBs). Light-assisted SSLOBs have been gradually explored as an ingenious system; however, the fundamental mechanisms of the SSCs interface behavior remain unclear. Here, we discovered that light assistance can enhance the fast inner-sphere charge transfer in SSCs and regulate the discharge products with spherical particles generated via the surface growth model. Moreover, the high photoelectron excitation and transportation capabilities of SSCs can retard cathodic catalytic decay by avoiding structural degradation of the cathode with a reduced charge voltage. The light-induced SSLOBs exhibited excellent stability (170â cycles) with a low discharge-charge polarization overpotential (0.27â V). Furthermore, transparent SSLOBs with exceptional flexibility, mechanical stability, and multiform shapes were fabricated for theory-to-practical applications in sunlight-induced batteries. Our study opens new opportunities for the introduction of solar energy into energy storage systems.
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In this study, we explored the potential of a newly prepared nano-zero valent zinc (nZVZn), biochar (BC)/nZVZn and BC/hydroxyapatite-alginate (BC/HA-alginate) composites for the removal of inorganic As species from water. Relatively, higher percentage removal of As(III) and As(V) was obtained by nZVZn at pH 3.4 (96% and 94%, respectively) compared to BC/nZVZn (90% and 88%) and BC/HA-alginate (88% and 80%) at pH 7.2. Freundlich model provided the best fit (R2 = up to 0.98) for As(III) and As(V) sorption data of all the sorbents, notably for nZVZn. The pseudo-second order model well-described kinetics of As(III) and As(V) (R2 = 0.99) sorption on all the sorbents. The desorption experiments demonstrated that the As removal efficiency, up to the third sorption/desorption cycle, was in the order of nZVZn â¼ BC/HA-alginate (88%) > BC/nZVZn (84%). The Fourier transform infrared spectroscopy depicted that the -OH, -COOH, Zn-O and Zn-OH surface functional groups were responsible for the sorption of As(III) or As(V) on the sorbents investigated here. This study highlights that removal of As species from water by BC/nZVZn composite can be compared with nZVZn, suggesting that integrating BC with nZVZn could efficiently remove As from As-contaminated drinking water.
This is the first study to explore the potential of a newly prepared sugarcane bagasse biochar/nano-zerovalent zinc (BC/nZVZn) based composite for the removal of inorganic arsenic (As) species from water. The results indicated high percentage removal of As(III) and As(V) from water by BC/nZVZn that were comparable to nZVZn alone.
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Arsénico , Contaminantes Químicos del Agua , Purificación del Agua , Zinc , Contaminantes Químicos del Agua/química , Adsorción , Purificación del Agua/métodos , Biodegradación Ambiental , Carbón Orgánico/química , Agua , CinéticaRESUMEN
We report a straightforward strategy to design efficient N doped porous carbon (NPC) electrocatalyst that has a high concentration of easily accessible active sites for the CO2 reduction reaction (CO2 RR). The NPC with large amounts of active N (pyridinic and graphitic N) and highly porous structure is prepared by using an oxygen-rich metal-organic framework (Zn-MOF-74) precursor. The amount of active N species can be tuned by optimizing the calcination temperature and time. Owing to the large pore sizes, the active sites are well exposed to electrolyte for CO2 RR. The NPC exhibits superior CO2 RR activity with a small onset potential of -0.35â V and a high faradaic efficiency (FE) of 98.4 % towards CO at -0.55â V vs. RHE, one of the highest values among NPC-based CO2 RR electrocatalysts. This work advances an effective and facile way towards highly active and cost-effective alternatives to noble-metal CO2 RR electrocatalysts for practical applications.
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In this study, mechanical vibration is used for hydrogen generation and decomposition of dye molecules, with the help of BiFeO3 (BFO) square nanosheets. A high hydrogen production rate of ≈124.1â µmol g-1 is achieved under mechanical vibration (100â W) for 1â h at the resonant frequency of the BFO nanosheets. The decomposition ratio of Rhodamineâ B dye reaches up to ≈94.1 % after mechanical vibration of the BFO catalyst for 50â min. The vibration-induced catalysis of the BFO square nanosheets may be attributed to the piezocatalytic properties of BFO and the high specific surface area of the nanosheets. The uncompensated piezoelectric charges on the surfaces of BFO nanosheets induced by mechanical vibration result in a built-in electric field across the nanosheets. Unlike a photocatalyst for water splitting, which requires a proper band edge position for hydrogen evolution, such a requirement is not needed in piezocatalytic water splitting, where the band tilting under the induced piezoelectric field will make the conduction band of BFO more negative than the H2 /H2 O redox potential (0â V) for hydrogen generation.
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High-temperature solid oxide electrolysis cells (SOECs) are advanced electrochemical energy storage and conversion devices with high conversion/energy efficiencies. They offer attractive high-temperature co-electrolysis routes that reduce extra CO2 emissions, enable large-scale energy storage/conversion and facilitate the integration of renewable energies into the electric grid. Exciting new research has focused on CO2 electrochemical activation/conversion through a co-electrolysis process based on the assumption that difficult C[double bond, length as m-dash]O double bonds can be activated effectively through this electrochemical method. Based on existing investigations, this paper puts forth a comprehensive overview of recent and past developments in co-electrolysis with SOECs for CO2 conversion and utilization. Here, we discuss in detail the approaches of CO2 conversion, the developmental history, the basic principles, the economic feasibility of CO2/H2O co-electrolysis, and the diverse range of fuel electrodes as well as oxygen electrode materials. SOEC performance measurements, characterization and simulations are classified and presented in this paper. SOEC cell and stack designs, fabrications and scale-ups are also summarized and described. In particular, insights into CO2 electrochemical conversions, solid oxide cell material behaviors and degradation mechanisms are highlighted to obtain a better understanding of the high temperature electrolysis process in SOECs. Proposed research directions are also outlined to provide guidelines for future research.
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A new type of Fe, N-doped hierarchically porous carbons (N-Fe-HPCs) has been synthesized via a cost-effective synthetic route, derived from nitrogen-enriched polyquaternium networks by combining a simple silicate templated two-step graphitization of the impregnated carbon. The as-prepared N-Fe-HPCs present a high catalytic activity for the oxygen reduction reaction (ORR) with onset and half-wave potentials of 0.99 and 0.86 V in 0.1 M KOH, respectively, which are superior to commercially available Pt/C catalyst (half-wave potential 0.86 V vs. RHE). Surprisingly, the diffusion-limited current density of N-S-HPCs approaches â¼7.5 mA cm(-2), much higher than that of Pt/C (â¼5.5 mA cm(-2)). As a cathode electrode material used in Zn-air batteries, the unique configuration of the N-Fe-HPCs delivers a high discharge peak power density reaching up to 540 mW cm(-2) with a current density of 319 mA cm(-2) at 1.0 V of cell voltage and an energy density >800 Wh kg(-1). Additionally, outstanding ORR durability of the N-Fe-HPCs is demonstrated, as evaluated by the transient cell-voltage behavior of the Zn-air battery retaining an open circuit voltage of 1.48 V over 10 hours with a discharge current density of 100 mA cm(-2).
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Electrolytes have been identified as some of the most influential components in the performance of electrochemical supercapacitors (ESs), which include: electrical double-layer capacitors, pseudocapacitors and hybrid supercapacitors. This paper reviews recent progress in the research and development of ES electrolytes. The electrolytes are classified into several categories, including: aqueous, organic, ionic liquids, solid-state or quasi-solid-state, as well as redox-active electrolytes. Effects of electrolyte properties on ES performance are discussed in detail. The principles and methods of designing and optimizing electrolytes for ES performance and application are highlighted through a comprehensive analysis of the literature. Interaction among the electrolytes, electro-active materials and inactive components (current collectors, binders, and separators) is discussed. The challenges in producing high-performing electrolytes are analyzed. Several possible research directions to overcome these challenges are proposed for future efforts, with the main aim of improving ESs' energy density without sacrificing existing advantages (e.g., a high power density and a long cycle-life) (507 references).
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This paper reviews recent progress made in identifying electrocatalysts for carbon dioxide (CO2) reduction to produce low-carbon fuels, including CO, HCOOH/HCOO(-), CH2O, CH4, H2C2O4/HC2O4(-), C2H4, CH3OH, CH3CH2OH and others. The electrocatalysts are classified into several categories, including metals, metal alloys, metal oxides, metal complexes, polymers/clusters, enzymes and organic molecules. The catalyts' activity, product selectivity, Faradaic efficiency, catalytic stability and reduction mechanisms during CO2 electroreduction have received detailed treatment. In particular, we review the effects of electrode potential, solution-electrolyte type and composition, temperature, pressure, and other conditions on these catalyst properties. The challenges in achieving highly active and stable CO2 reduction electrocatalysts are analyzed, and several research directions for practical applications are proposed, with the aim of mitigating performance degradation, overcoming additional challenges, and facilitating research and development in this area.
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In this review, we examine the most recent progress and research trends in the area of alkaline polymer electrolyte membrane (PEM) development in terms of material selection, synthesis, characterization, and theoretical approach, as well as their fabrication into alkaline PEM-based membrane electrode assemblies (MEAs) and the corresponding performance/durability in alkaline polymer electrolyte membrane fuel cells (PEMFCs). Respective advantages and challenges are also reviewed. To overcome challenges hindering alkaline PEM technology advancement and commercialization, several research directions are then proposed.
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The electrochemical reduction of CO2 (ERCO2) has emerged as one of the most promising methods for achieving both renewable energy storage and CO2 recovery. However, achieving both high selectivity and stability of catalysts remains a significant challenge. To address this challenge, this study investigated the selective synthesis of formate via ERCO2 at the interface of In2O3 and Bi2O3 in the InBiO6 composite material. Moreover, InBiO6 was synthesized using indium-based metal-organic frameworks as precursor, which underwent continuous processing through ion exchange and thermal reduction. The results revealed that the formate Faradaic efficiency (FEformate) of InBiO6 reached nearly 100 % at -0.86 V vs. reversible hydrogen electrode (RHE) and remained above 90 % after continuous 317-h electrolysis, which exceeded those of previously reported indium-based catalysts. Additionally, the InBiO6 composite material exhibited an FEformate exceeding 80 % across a wide potential range of 500 mV from -0.76 to -1.26 V vs. RHE. Density-functional theory analysis confirmed that the heterogeneous interface of InBiO6 played a role in achieving optimal free energies for *OCHO on its surface. Furthermore, the addition of Bi to the InBiO6 matrix facilitated electron transfer and altered the electronic structure of In2O3, thereby enhancing the adsorption, decomposition, and formate production of *OCHO.
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Electrochemical conversion of carbon dioxide (CO2) into syngas is considered a promising approach to mitigate global warming and achieve the recycling of carbon resources. In this work, a series of core-shell metal (copper/indium) oxides with abundant grain boundaries (GBs) between the amorphous In2O3 and cubic Cu2O have been prepared by template-assisted co-precipitation method and tested for the synthesis of syngas by electrochemical CO2 reduction reaction (CO2RR). The phases of Cu2O and In2O3 are independent in bimetallic oxides and do not form any alloy oxidation phase, thus Cu2O and In2O3 can maintain their crystal structure and chemical properties in bimetallic oxides. The Cu2O and In2O3 would been completely reduced to metallic Cu and In during CO2RR. The derived copper/indium possesses the maximum FE of CO (80 %) at -0.77 V vs. reversible hydrogen electrode (RHE) and a good stability of 10 h in an H-type cell. Further applied the copper/indium oxide in the MEA reactor, the FE of CO is more than 80 % at 2.6 V and the total FE of syngas is near 100 % at all applied potentials. More importantly, the H2/CO ratios can be tuned from 1/1 to 1/4 by changing the applied voltages in MEA. Therefore, this study provides a promising strategy to promote the electrocatalytic CO2RR conversion by creating abundant grain boundaries in bimetallic oxides to regulate the ratio of H2/CO.
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This study investigated the impact of chitosan (CH, 1%) and aloe vera gel (AL, 30%) edible coatings on the preservation of blue honeysuckle quality during a 28-day storage at -1 °C. Coating with CH, AL, and CH+AL led to notable enhancements in several key attributes. These included increased firmness, total soluble solids, acidity, pH, and antioxidant capacity (measured through DPPH, ABTS, and FRAP assays), as well as the preservation of primary (ascorbic acid) and secondary metabolites (TPC, TAC, and TFC). The TAC and TFC levels were approximately increased by 280% and 17%, respectively, in coated blue honeysuckle after 28 d compared to uncoated blue honeysuckle. These coatings also resulted in reduced weight loss, respiration rate, color, abscisic acid, ethylene production, and malondialdehyde content. Notably, the CH+AL treatment excelled in preserving secondary metabolites and elevating FRAP-reducing power, demonstrating a remarkable 1.43-fold increase compared to the control after 28 days. Overall, CH+AL exhibited superior effects compared to CH or AL treatment alone, offering a promising strategy for extending the shelf life and preserving the quality of blue honeysuckle during storage.
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Rational construction of efficient bifunctional catalysts with robust catalytic activity and durability is significant for overall water splitting (conversion between water and hydrogen fuel/oxygen) using non-precious metal systems. In this work, the hierarchically porous N, P, O-doped transition metal phosphate in the Ni foam (NF) electrode (hollow flower-like NPO/NixPy@NF) was prepared through facile hydrothermal method coupled with phosphorization treatment. The hierarchical hollow flower-like NPO/NixPy@NF electrodes exhibited high bifunctional activity and stability for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline solutions. The optimized electrode showed low overpotentials of 76 and 240 mV for HER and OER to reach a current density of 10 mA cm-2, respectively. Notably, the NPO/NixPy@NF electrode only required a low voltage of 1.99 V to reach the current densities of 100 mA cm-2 with long-term stability for overall water splitting using the NPO/NixPy@NF|| NPO/NixPy@NF cell, surpassing that of the Pt/C-RuO2 (2.24 V@ 100 mA cm-2). The good catalytic and battery performance should be attributed to i) the open hierarchical structure that enhanced the mass transfer; ii) a highly conductive substrate that accelerated the electron transfer; iii) the rich heterojunction and strong synergy between Ni2P and Ni5P4 that improved the catalytic kinetic; iv) the proper-thickness amorphous phosphorus oxide nitride (PON) shell that realized the stability. This work demonstrates a promising methodology for designing bifunctional transition metal phosphides with high performance for efficient water splitting.
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The alkaline solid-state electrolytes have received widespread attention for their good safety and electrochemical stability. However, they still suffer from low conductivity and poor mechanical properties. Herein, we report the synthesis of double-network featured hydroxide-conductive membranes fabricated by polyvinyl alcohol (PVA) and chitosan (CS) as the double-skeletons. Then, we implanted quaternary ammonium salt guar hydroxypropyltrimonium chloride (GG) as the OH- conductor for high-performance electrochemical devices. By virtue of the unique stripe-like structure shared from the double skeleton with a high degree of compatibility and stronger hydrogen bond interactions, the polyvinyl alcohol/chitosan-guar hydroxypropyltrimonium chloride (PCG) solid-state electrolytes achieved optimal thermal stability (> 300 °C), mechanical property (â¼ 34.15 MPa), dimensional stability (at any bending angle), and high ionic conductivity (13 mS cm-1) and ion mobility number (tion â¼ 0.90) compared with chitosan-guar hydroxypropyltrimonium chloride (CG) and polyvinyl alcohol-guar hydroxypropyltrimonium chloride (PG) electrolyte membrane. As a proof-of-concept application, the "sandwich"-type zinc-air battery (ZAB) assembled using PCG membrane as the electrolyte realized a high open-circuit voltage (1.39 V) and an excellent power density (128 mW cm-2). Notably, in addition to its long-term cycle life (30 h, 2 mA cm-2) and stable discharge plateau (12 h, 5 mA cm-2), it could even enable a flexible ZAB (F-ZAB) to readily power light-emitting diodes (LED) at any bending angle. These merits afford the PCG membrane a promising electrolyte for improving the performance of solid-state batteries.
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The objectives of this research were to analyze anthocyanins in blue honeysuckle (Lonicera caerulea L.), bilberry (Vaccinium vitis-idaea L), and cranberry (Vaccinium macrocarpon Ait.), using HPLC-ESI-QTOF-MS2, Fourteen, fifteen, and eight anthocyanins were identified in blue honeysuckle, bilberry, and cranberry, respectively. Cyanidin-3-glucoside (C3G) and peonidin-3-glucoside were detected in all three types of berries, with blue honeysuckle showing the highest C3G content at 5686.28 mg/100 g DW. Total phenolic content (TPC) and total flavonoid content (TFC), along with ABTS, DPPH, and FRAP assays, were measured. Blue honeysuckle exhibited the highest levels of TPC and TFC. The SOD, POD, and CAT activities in blue honeysuckle were 1761.17 U/g, 45,525.65 U/g, and 1043.24 U/g, respectively, which were significantly superior to those in bilberry and cranberry. The antioxidant mechanisms of these enzymes were investigated by molecular docking, C3G showed a higher affinity for POD, confirming the effectiveness of C3G as an antioxidant.
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The Zn dendrite limits the practical application of aqueous zinc-ion batteries in the large-scale energy storage systems. To suppress the growth of Zn dendrites, a zinc ionophore of hydroxychloroquine (defined as HCQ) applied in vivo treatment is investigated as the electrolyte additive. HCQ dynamically regulates zinc ion concentration in the outer Helmholtz layer, promoting even Zn plating at the anode/electrolyte interface. This is evidenced by the scanning electron microscopy, which delivers planar Zn plating after cycling. It is further supported by the X-ray diffraction spectroscopy, which reveals the growth of Zn (002) plane. Additionally, the reduced production of H2 during Zn plating/stripping is detected by the in-situ differential electrochemical mass spectrometry (DEMS), which shows the resistance of Zn (002) to hydrogen evolution reaction. The mechanism of dynamic regulation for zinc ion concentration is demonstrated by the in-situ optical microscopy. The hydrated zinc ion can be further plated more rapidly to the uneven location than the case in other regions, which is resulted from the dynamic regulation for zinc ion concentration. Therefore, the uniform Zn plating is formed. A cycling life of 1100 h is exhibited in the Zn||Zn symmetric cell at 1.6 mA cm-2 with the capacity of 1.6 mAh cm-2. The Zn||Cu battery exhibits a cycling life of 200 cycles at 4 mA cm-2 with a capacity of 4 mAh cm-2 and the average Coulombic efficiency is larger than 99 %. The Zn||VO2 battery with HCQ modified electrolyte can operate for 1500 cycles at 4 A g-1 with a capacity retention of 90 %. This strategy in the present work is wished to advance the development of zinc-ion batteries for practical application.
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The utilization of biowastes for producing biochar to remove potentially toxic elements from water represents an important pathway for aquatic ecosystem decontamination. Here we explored the significance of thiol-functionalization on sugarcane bagasse biochar (Th/SCB-BC) and rice husk biochar (Th/RH-BC) to enhance arsenite (As(III)) removal capacity from water and compared their efficiency with both pristine biochars (SCB-BC and RH-BC). The maximum As(III) sorption was found on Th/SCB-BC and Th/RH-BC (2.88 and 2.51 mg g-1, respectively) compared to the SCB-BC and RH-BC (1.51 and 1.40 mg g-1). Relatively, a greater percentage of As(III) removal was obtained with Th/SCB-BC and Th/RH-BC (92% and 83%, respectively) at a pH 7 compared to pristine SCB-BC and RH-BC (65% and 55%) at 6 mg L-1 initial As(III) concentration, 2 h contact time and 1 g L-1 sorbent dose. Langmuir (R2 = 0.99) isotherm and pseudo-second-order kinetic (R2 = 0.99) models provided the best fits to As(III) sorption data. Desorption experiments indicated that the regeneration ability of biochars decreased and it was in the order of Th/SCB-BC (88%) > Th/RH-BC (82%) > SCB-BC (77%) > RH-BC (69%) up to three sorption-desorption cycles. Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy results demonstrated that the thiol (-S-H) functional groups were successfully grafted on the surface of two biochars and as such contributed to enhance As(III) removal from water. Spectroscopic data indicated that the surface functional moieties, such as -S-H, - OH, - COOH, and C = O were involved to increase As(III) sorption on thiol-functionalized biochars. This study highlights that thiol-grafting on both biochars, notably on SCB-BC, enhanced their ability to remove As(III) from water, which can be used as an effective technique for the treatment of As from drinking water.
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Arsenitos , Celulosa , Carbón Orgánico , Oryza , Saccharum , Contaminantes Químicos del Agua , Carbón Orgánico/química , Saccharum/química , Oryza/química , Adsorción , Arsenitos/química , Contaminantes Químicos del Agua/química , Celulosa/química , Compuestos de Sulfhidrilo/químicaRESUMEN
Blue honeysuckle is a source of anthocyanins with great potential as a food colorant, and a healthy and functional food material, and contains much cyanidin 3-glucoside (C3G), which has many benefits for human health. A rapid, reliable, accurate quantification method of anthocyanin content in different varieties of blue honeysuckle is critical to help in breeding and selecting excellent varieties which are used in the food processing industry and healthcare industry. Our objective was to verify the modified quantification method of C3G and quantified C3G content in three blue honeysuckle varieties of 'Berel', 'Lanjingling' and 'Wulan' using the modified HPLC method by Agilent 1200 system and CAPCELL PAK C18 column (150 mmâ ¹4.6 mm, I. D., 5 µm, Japan), with detection at 530 nm, the solvent flow rate was 1 mL/min, the temperature of the column chamber is 35 °C. The results indicated that the modified method was validated in terms of linearity (R2 = 0.999), precision (RSD = 0.61%), stability (RSD = 5.23%), and recovery with a good level, and C3G can be quickly quantified in blue honeysuckle. In addition, 'Wulan' contains the highest C3G level compared with 'Lanjingling' and 'Berel'.
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In this paper, the structures of polyphenols and their bioactivity of black mulberry (Morus nigra L.) cv. 'Heisang No. 1' were comprehensively analyzed. The 11 anthocyanins and 20 non-anthocyanin phenolic compounds were identified and quantified by liquid chromatography high-resolution time-of-flight mass spectrometry (LC-HR-TOF/MS2). The cyanidin-3-glucoside and cyanidin-3-rutinoside were the major anthocyanins in the black mulberry. In addition, the black mulberry showed potent antioxidant capacity as assessed by DPPH, ABTS, and FRAP assays. Black mulberry anthocyanins exhibited stronger inhibition activities against α-amylase, α-glucosidase, and lipase compared to non-anthocyanin polyphenols, with IC50 values of 1.10, 4.36, and 9.18 mg/mL, respectively. The total anthocyanin content of black mulberry crude extracts and anthocyanins was 570.10 ± 77.09 and 1278.23 ± 117.60 mg C3GE/100 g DW, respectively. Black mulberry may be a rich source of polyphenols, natural antioxidants, and effective antidiabetic substances with great potential in the food industry.