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Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution.
Sastri, Chivukula V; Sook Seo, Mi; Joo Park, Mi; Mook Kim, Kwan; Nam, Wonwoo.
Affiliation
  • Sastri CV; Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womens University, Seoul 120-750, Korea.
Chem Commun (Camb) ; (11): 1405-7, 2005 Mar 21.
Article in En | MEDLINE | ID: mdl-15756318
ABSTRACT
A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.
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Collection: 01-internacional Database: MEDLINE Main subject: Sulfides / Nonheme Iron Proteins / Iron Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2005 Type: Article
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Collection: 01-internacional Database: MEDLINE Main subject: Sulfides / Nonheme Iron Proteins / Iron Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2005 Type: Article