1,1'-(Ethane-1,2-di-yl)dipyridinium dichromate(VI).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 3): m305, 2012 Mar 01.
Article
in En
| MEDLINE
| ID: mdl-22412447
In the cation of the title salt, (C(12)H(14)N(2))[Cr(2)O(7)], the two pyridinium moieties are in an anti orientation with respect to one another. The dihedral angle between the pyridine rings is 6.3â
(2)°. The N-C-C-N torsion angle is 177.5â
(2)°. In the dianion, the Cr(VI) ions are in a slightly distorted tetra-hedral coordination environment and the bond angles at the independent Cr(VI) ions are in the ranges 105.93â
(10)-110.60â
(11) and 107.35â
(11)-111.07â
(12)°. The Cr-O-Cr angle is 127.96â
(12)°. The crystal used was an inversion twin with refined components of 0.510â
(19) and 0.490â
(19).
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Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr Sect E Struct Rep Online
Year:
2012
Type:
Article