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Iron-catalyzed N-alkylation using π-activated ethers as electrophiles.
Fan, Xiaohui; Fu, Lin-An; Li, Na; Lv, Hao; Cui, Xiao-Meng; Qi, Yuan.
Affiliation
  • Fan X; School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China. fanxh@mail.lzjtu.cn
Org Biomol Chem ; 11(13): 2147-53, 2013 Apr 07.
Article in En | MEDLINE | ID: mdl-23380886
ABSTRACT
A new method for the synthesis of diverse N-alkylation compounds was developed via an iron-catalyzed etheric C(sp(3))-O cleavage with the C-N bond formation in the reaction of π-activated ethers with various nitrogen-based nucleophiles. In addition, the mechanism of this reaction was investigated.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Ferric Compounds / Ethers / Amines Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2013 Type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Ferric Compounds / Ethers / Amines Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2013 Type: Article Affiliation country: China