Mild and chemoselective lactone ring-opening with (TMS)ONa. Mechanistic studies and application to sweroside derivatives.

Lemoine, Hugues; Markovic, Dean; Deguin, Brigitte

Lemoine, Hugues; Markovic, Dean; Deguin, Brigitte.

Affiliation

Lemoine H; Laboratoire de Pharmacognosie, Faculté des Sciences Pharmaceutiques et Biologiques, Université Paris Descartes, Sorbonne Paris Cité, UMR/CNRS No. 8638 , 4 Avenue de l'Observatoire, F-75006 Paris, France.

J Org Chem ; 79(10): 4358-66, 2014 May 16.

Article in En | MEDLINE | ID: mdl-24738692

Subject(s)

Iridoid Glucosides/chemistry; Lactones/chemistry; Sodium/chemistry; Solvents/chemistry; Trimethylsilyl Compounds/chemistry; Kinetics; Molecular Structure; Stereoisomerism

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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Sodium / Solvents / Trimethylsilyl Compounds / Iridoid Glucosides / Lactones Language: En Journal: J Org Chem Year: 2014 Type: Article Affiliation country: France

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