Stereospecific and stereoselective rhodium(I)-catalyzed intramolecular [2+2+2] cycloaddition of allene-ene-ynes: construction of bicyclo[4.1.0]heptenes.

Ohta, Yuu; Yasuda, Shigeo; Yokogawa, Yuka; Kurokawa, Kei; Mukai, Chisato

Ohta, Yuu; Yasuda, Shigeo; Yokogawa, Yuka; Kurokawa, Kei; Mukai, Chisato.

Affiliation

Ohta Y; Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan).

Angew Chem Int Ed Engl ; 54(4): 1240-4, 2015 Jan 19.

Article in En | MEDLINE | ID: mdl-25353655

Subject(s)

Bridged Bicyclo Compounds/chemistry; Rhodium/chemistry; Alkynes/chemistry; Catalysis; Cycloaddition Reaction; Cyclopropanes/chemistry; Stereoisomerism

Key words

alkynes; allenes; cycloadditions; diastereoselectivity; rhodium

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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Rhodium / Bridged Bicyclo Compounds Language: En Journal: Angew Chem Int Ed Engl Year: 2015 Type: Article

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