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Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones.
Walker, S E; Lamb, C J C; Beattie, N A; Nikodemiak, P; Lee, A-L.
Affiliation
  • Walker SE; Institute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK. A.Lee@hw.ac.uk.
Chem Commun (Camb) ; 51(19): 4089-92, 2015 Mar 07.
Article in En | MEDLINE | ID: mdl-25665602
ABSTRACT
Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Cyclopentanes / Ketones Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2015 Type: Article Affiliation country: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Cyclopentanes / Ketones Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2015 Type: Article Affiliation country: United kingdom