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A Piezochromic Dysprosium(III) Single-Molecule Magnet Based on an Aggregation-Induced-Emission-Active Tetraphenylethene Derivative Ligand.
Chen, Wen-Bin; Chen, Yan-Cong; Liu, Jun-Liang; Jia, Jian-Hua; Wang, Long-Fei; Li, Quan-Wen; Tong, Ming-Liang.
Affiliation
  • Chen WB; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, P. R. China.
  • Chen YC; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, P. R. China.
  • Liu JL; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, P. R. China.
  • Jia JH; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, P. R. China.
  • Wang LF; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, P. R. China.
  • Li QW; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, P. R. China.
  • Tong ML; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University , Guangzhou 510275, P. R. China.
Inorg Chem ; 56(15): 8730-8734, 2017 Aug 07.
Article in En | MEDLINE | ID: mdl-28692252
ABSTRACT
A bifunctional dysprosium(III) dimer, [Dy2(HTPEIPOMe)2(OAc)4(NO3)2] (1), comprising an AIE-active (AIE = aggregation-induced emission) ligand of 2-methoxy-6-[[[4-(1,2,2-triphenylvinyl)phenyl]imino]methyl]phenol (HTPEIPOMe), was successfully synthesized. It not only behaves as a single-molecule magnet (SMM) with an energy barrier of 168(15) K at zero field but also exhibits piezochromism during the pressing-fuming cycle with switchable color, photoluminescence, and magnetic response.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2017 Type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2017 Type: Article