Homoleptic Trifluoromethyl Derivatives of AgI and AgIII.
Chemistry
; 24(50): 13098-13101, 2018 Sep 06.
Article
in En
| MEDLINE
| ID: mdl-29981177
ABSTRACT
The homoleptic silver(I) compound [PPh4 ][CF3 AgCF3 ] (1) provides a convenient entry to the homoleptic silver(III) derivative [PPh4 ][Ag(CF3 )4 ] (2). Once isolated as pure substances, these compounds exhibit marked thermal stabilities. Their structural and spectroscopic properties have been experimentally established. Moreover, their electronic structures have been calculated by theoretical methods. The electronic structure of the oxidized species [Ag(CF3 )4 ]- provides a new case of ligand-field inversion caused by the CF3 ligands.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chemistry
Journal subject:
QUIMICA
Year:
2018
Type:
Article
Affiliation country:
Spain