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A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity.
Neniskis, Algirdas; Rackauskaite, Dovile; Shi, Qixun; Robertson, Aiden J; Marsh, Andrew; Ulcinas, Arturas; Valiokas, Ramunas; Brown, Steven P; Wärnmark, Kenneth; Orentas, Edvinas.
Affiliation
  • Neniskis A; Department of Organic Chemistry, Vilnius University, Vilnius, Lithuania.
  • Rackauskaite D; Department of Organic Chemistry, Vilnius University, Vilnius, Lithuania.
  • Shi Q; Center for Analysis and Synthesis, Department of Chemistry, Lund University, Lund, Sweden.
  • Robertson AJ; Department of Physics and Department of Chemistry, University of Warwick, Coventry, UK.
  • Marsh A; Department of Physics and Department of Chemistry, University of Warwick, Coventry, UK.
  • Ulcinas A; Department of Nanoengineering, Center for Physical Sciences and Technology, Vilnius, Lithuania.
  • Valiokas R; Department of Nanoengineering, Center for Physical Sciences and Technology, Vilnius, Lithuania.
  • Brown SP; Department of Physics and Department of Chemistry, University of Warwick, Coventry, UK.
  • Wärnmark K; Center for Analysis and Synthesis, Department of Chemistry, Lund University, Lund, Sweden.
  • Orentas E; Department of Organic Chemistry, Vilnius University, Vilnius, Lithuania.
Chemistry ; 24(53): 14028-14033, 2018 Sep 20.
Article in En | MEDLINE | ID: mdl-30070741
A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by 1 H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2018 Type: Article Affiliation country: Lithuania
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PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2018 Type: Article Affiliation country: Lithuania