Synergetic integration of thermal conductivity and flame resistance in nacre-like nanocellulose composites.
Carbohydr Polym
; 264: 118058, 2021 Jul 15.
Article
in En
| MEDLINE
| ID: mdl-33910753
ABSTRACT
Highly thermally conductive and flame resistant nanocellulose-based composites can synchronously achieve efficient thermal dissipation and low fire hazards of electronic devices, which shows great promise in next-generation green and flexible electronics. However, it has long been intractable to optimize the high thermal conductivity (TC) and flame resistance simultaneously. Herein, synergetic integration of high TC and flame resistance in nacre-like nanocellulose composites has been successfully achieved by the vacuum-assisted filtration of cellulose nanofibers (CNFs) and functionalized boron nitride nanosheets (BNNS-p-APP). Benefiting from the highly oriented hierarchical microstructure, strong hydrogen-bonding interaction, and successful immobilization of ammonium polyphosphate (APP), the as-obtained CNFs/BNNS-p-APP composite film achieves a high in-plane TC of 9.1â¯Wâ¯m-1â¯K-1 and outstanding flame resistance. Meantime, this eco-friendly nanocellulose-based composite also exhibits remarkable flexibility, folding endurance, and mechanical robustness, robustness, which may open up a new opportunity for the thermal management of flexible electronics.
Key words
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Main subject:
Cellulose
/
Nanocomposites
/
Nacre
/
Flame Retardants
Limits:
Humans
Language:
En
Journal:
Carbohydr Polym
Year:
2021
Type:
Article