A nitrogen-doped asymmetric phenalenyl with a zwitterionic ground state.
Chem Commun (Camb)
; 57(68): 8433-8436, 2021 Sep 04.
Article
in En
| MEDLINE
| ID: mdl-34338698
ABSTRACT
Herein, an asymmetric N-doped phenalenyl (BTAP) compound has been synthesized and carefully studied for the first time. The synthesis of BTAP reveals a planar configuration and an unexpected zwitterionic ground state with the negative charge delocalized around the circumjacent part and the positive charge mainly localized on the center.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2021
Type:
Article