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9-Cyano-10-methoxycarbonylanthracene as a Visible Organic Photoredox Catalyst in the Two-Molecule Photoredox System.
Tajimi, Yuka; Nachi, Yasuhiro; Inada, Ryoko; Hashimoto, Ryoga; Yamawaki, Mugen; Ohkubo, Kei; Morita, Toshio; Yoshimi, Yasuharu.
Affiliation
  • Tajimi Y; Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan.
  • Nachi Y; Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan.
  • Inada R; Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan.
  • Hashimoto R; Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan.
  • Yamawaki M; Department of Chemistry and Biology, National Institute of Technology, Fukui College, Genshi-cho, Fukui 916-8507, Japan.
  • Ohkubo K; Institute for Advanced Co-creation Studies, Osaka University, 2-8 Yamada-oka, Suita, Osaka 565-0871, Japan.
  • Morita T; Institute for Open and Transdisciplinary Research Initiatives, Osaka University, 2-8 Yamada-oka, Suita, Osaka 565-0871, Japan.
  • Yoshimi Y; Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan.
J Org Chem ; 87(11): 7405-7413, 2022 Jun 03.
Article in En | MEDLINE | ID: mdl-35604396
Visible-light-induced decarboxylative and deboronative reactions using two-molecule organic photoredox catalysts, namely, phenanthrene (Phen) and biphenyl (BP), as electron donors and 9-cyano-10-methoxycarbonylanthracene 1a as an electron acceptor were achieved. The high solubility of 1a significantly improved the reaction efficiency and product yield. In addition, the facile tuning of the oxidation potential of the electron-donor molecule via the replacement of Phen with BP enabled the application of the two-molecule photoredox system to a wide range of substrates.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2022 Type: Article Affiliation country: Japan
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PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2022 Type: Article Affiliation country: Japan