Your browser doesn't support javascript.
loading
A Stable 3d-4f Heterometallic Cluster with Magneto-Optical Activity.
Li, Yan; Yang, Yan-Duan; Ge, Rui; Lv, Zhi-Hao; Tian, Chong-Bin; Wei, Biao-Wen; Li, Xin-Xiong; Zhuang, Nai-Feng; Zheng, Shou-Tian.
Affiliation
  • Li Y; College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
  • Yang YD; College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
  • Ge R; College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
  • Lv ZH; College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
  • Tian CB; State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
  • Wei BW; College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518055 China.
  • Li XX; College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
  • Zhuang NF; State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
  • Zheng ST; College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
Inorg Chem ; 61(23): 8746-8751, 2022 Jun 13.
Article in En | MEDLINE | ID: mdl-35642949
A stable 3d-4f heterometallic cluster, namely, {Dy4Ni5L10(NO3)4(CO3)4(CH3OH)2}·CH3CN (Dy4Ni5, HL = 8-hydroxyquinoline), has been solvothermally synthesized and structurally characterized. The compound exhibits an interesting structure in which a tetrahedron based on 4f ions interpenetrates with a square pyramid based on 3d ions. Besides, a unique intermolecular interaction was found in Dy4Ni5, giving rise to its high stability not only when it is in the solid state but also when it dissolves in organic solvents. In addition, the magnetic behavior of solid Dy4Ni5 and the magneto-optical activity of the Dy4Ni5 solution were also studied.
Fulltext
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2022 Type: Article Affiliation country: China
Fulltext
Print
XML
PubMed Links
Search on Google

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Inorg Chem Year: 2022 Type: Article Affiliation country: China