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Electricity-Promoted Friedel-Crafts Acylation of Biarylcarboxylic Acids.
Liu, Chen; Yu, Jiage; Bao, Liang; Zhang, Gaoyuan; Zou, Xinyue; Zheng, Bing; Li, Yiyi; Zhang, Yunfei.
Affiliation
  • Liu C; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
  • Yu J; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
  • Bao L; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
  • Zhang G; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
  • Zou X; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
  • Zheng B; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
  • Li Y; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
  • Zhang Y; Department of Chemistry, China Agricultural University, Beijing 100193, P. R. China.
J Org Chem ; 88(6): 3794-3801, 2023 Mar 17.
Article in En | MEDLINE | ID: mdl-36861957
An electricity-promoted method for Friedel-Crafts acylation of biarylcarboxylic acids is described in this research. Various fluorenones can be accessed in up to 99% yields. During the acylation, electricity plays an essential role, which might motivate the chemical equilibrium by consuming the generated TFA. This study is predicted to provide an avenue to realize Friedel-Crafts acylation in a more environmentally friendly process.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2023 Type: Article
Fulltext
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PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2023 Type: Article