Preparation of Fe-BN-C catalysts derived from ZIF-8 and their performance in the oxygen reduction reaction.

ABSTRACT

Enhancing the oxygen reduction reaction (ORR) activity and stability of the fuel cell cathode electrocatalysts and reducing their costs are critical. In response to this need, Fe, B, and N co-doped hollow mesoporous carbon materials were prepared by a simple chemical doping one-step pyrolysis method using ZIF-8 as a precursor. The results showed that the optimized catalyst displayed a higher limiting current density (6.154 mA cm-2) and half-wave potential (0.859 V), which showed significant enhancement compared with the Pt/C catalyst (5.487 mA cm-2 and 0.853 V). Moreover, the optimized catalyst had outstanding long-term stability with a current density retention higher than 91% after 36 000 s of stability testing. This work provides a facile strategy for the design of outstanding ORR performance of non-precious metal oxygen reduction catalysts.