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Visible-light-promoted regioselective hydrocarboxylation of allenes with formate salt and CO2.
Zhang, Xian-Ming; Liu, Bao-En; Zhang, Zhen-Qiang; Zhan, Zhuang-Ping.
Affiliation
  • Zhang XM; Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361001 Fujian, People's Republic of China. zpzhan@xmu.edu.cn.
  • Liu BE; Gulei Innovation Institute, Xiamen University, Zhangzhou 363100, Fujian, People's Republic of China.
  • Zhang ZQ; Yunnan Precious Metals Laboratory Company, Ltd, Kunming 650106, Yunnan, People's Republic of China. zhenqiang.zhang@163.com.
  • Zhan ZP; Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361001 Fujian, People's Republic of China. zpzhan@xmu.edu.cn.
Org Biomol Chem ; 22(16): 3245-3248, 2024 Apr 24.
Article in En | MEDLINE | ID: mdl-38567821
ABSTRACT
Visible-light-promoted hydrocarboxylation of allenes with formate salt and CO2 was developed for the first time using commercially available [Ir(ppy)2(dtbbpy)]PF6 as a photocatalyst. This strategy provides an efficient and practical method to access ß,γ-unsaturated linear carboxylic acids in moderate yields with complete regioselectivity.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2024 Type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2024 Type: Article